Huang, Yingsi. / Thesis (M.Phil.)--Chinese University of Hong Kong, 2009. / Includes bibliographical references (leaves 105-106). / Abstracts in English and Chinese. / Abstract --- p.i / Abstract (in Chinese) --- p.iii / Acknowledgment --- p.v / Table of Contents --- p.vii / List of Figures --- p.x / List of Schemes --- p.xv / List of Tables --- p.xv / Abbreviations --- p.xvi / Chapter Chapter 1 --- Introduction --- p.1 / Chapter 1.1 --- Natural Photosynthesis --- p.1 / Chapter 1.1.1 --- Process of Natural Photosynthesis --- p.1 / Chapter 1.1.2 --- Chromophores of Natural Photosynthesis --- p.2 / Chapter 1.1.3 --- Mechanism of Natural Photosynthesis --- p.3 / Chapter 1.2 --- Development of Artificial Photosynthetic Models --- p.4 / Chapter 1.2.1 --- Models Based on Porphyrins and Fullerene Derivatives --- p.6 / Chapter 1.2.2 --- Models Based on Boron Dipyrromethenes (BDPs) --- p.12 / Chapter 1.2.3 --- Applications of Artificial Photosynthetic Models --- p.14 / Chapter 1.3 --- Boron Dipyrromethenes (BDPs) --- p.15 / Chapter 1.3.1 --- General --- p.15 / Chapter 1.3.2 --- Energy Transfer Systems Based on BDPs --- p.16 / Chapter 1.3.2.1 --- BDPs as Energy Donors --- p.16 / Chapter 1.3.2.2 --- BDPs as Energy Acceptors --- p.22 / Chapter 1.3.2.3 --- BDPs as both Energy Donors and Acceptors --- p.26 / Chapter 1.4 --- References --- p.30 / Chapter Chapter 2 --- "Synthesis, Characterization, and Photophysical Properties of the Triad BDP-SiPc-MSBDP as an Artificial Photosynthetic Model" --- p.35 / Chapter 2.1 --- Introduction --- p.35 / Chapter 2.2 --- Results and Discussion --- p.38 / Chapter 2.2.1 --- Preparation and Characterization --- p.38 / Chapter 2.2.2 --- Electronic Absorption and Photophysical Properties --- p.45 / Chapter 2.2.3. --- Electrochemical Properties --- p.50 / Chapter 2.3 --- Conclusion --- p.52 / Chapter 2.4 --- Experimental Section --- p.52 / Chapter 2.4.1 --- General --- p.52 / Chapter 2.4.2 --- Photophysical Studies --- p.53 / Chapter 2.4.3 --- Electrochemical Studies --- p.54 / Chapter 2.4.4 --- Synthesis --- p.54 / Chapter 2.5 --- References --- p.58 / Chapter Chapter 3 --- "Synthesis, Characterization, and Photophysical Properties of the Pentad SiPc(MSBDP-BDP)2" --- p.60 / Chapter 3.1 --- Introduction --- p.60 / Chapter 3.2 --- Results and Discussion --- p.61 / Chapter 3.2.1 --- Preparation and Characterization --- p.61 / Chapter 3.2.2 --- Ground-State Electronic Properties and Energy Transfer Processes of BDP-MSBDP 3.3 --- p.66 / Chapter 3.2.3 --- Photophysical Properties of the Pentad SiPc(MSBDP-BDP)2 (3.1) --- p.68 / Chapter 3.2.4 --- Electrochemical Properties of the Pentad SiPc(MSBDP-BDP)2 (3.1) --- p.73 / Chapter 3.3 --- Conclusion --- p.75 / Chapter 3.4 --- Experimental Section --- p.75 / Chapter 3.4.1 --- General --- p.75 / Chapter 3.4.2 --- Synthesis --- p.75 / Chapter 3.5 --- References --- p.80 / Chapter Chapter 4 --- Novel Artificial Photosynthetic Models Constructed by Supramolecular Methodology --- p.81 / Chapter 4.1 --- Introduction --- p.81 / Chapter 4.2 --- Results and Discussion --- p.83 / Chapter 4.2.1 --- Preparation and Characterization --- p.83 / Chapter 4.2.2 --- Ground-state Electronic Properties and Energy Transfer Process of Compound 4.6 --- p.86 / Chapter 4.2.3 --- Formation and Properties of Assembly 4.1 (ZnTPP.4.6) --- p.89 / Chapter 4.2.4 --- Formation and Properties of Assembly 4.2 [Ru(CO)TPP.4.6] --- p.95 / Chapter 4.2.5 --- Comparison of the Assemblies 4.1 and 4.2 --- p.100 / Chapter 4.3 --- Conclusion --- p.101 / Chapter 4.4 --- Experimental Section --- p.101 / Chapter 4.4.1 --- General --- p.101 / Chapter 4.4.2 --- Synthesis --- p.102 / Chapter 4.5 --- References --- p.105
| Identifer | oai:union.ndltd.org:cuhk.edu.hk/oai:cuhk-dr:cuhk_326782 |
| Date | January 2009 |
| Contributors | Huang, Yingsi., Chinese University of Hong Kong Graduate School. Division of Chemistry. |
| Source Sets | The Chinese University of Hong Kong |
| Language | English, Chinese |
| Detected Language | English |
| Type | Text, bibliography |
| Format | print, xvii, 114 leaves : ill. (some col.) ; 30 cm. |
| Rights | Use of this resource is governed by the terms and conditions of the Creative Commons “Attribution-NonCommercial-NoDerivatives 4.0 International” License (http://creativecommons.org/licenses/by-nc-nd/4.0/) |
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