The vibrational spectra of $( eta sp5$-C$ sb5$H$ sb5$)Re(CO)$ sb3, ( eta sp5$-C$ sb5$Me$ sb5$)Re(CO)$ sb3, ( eta sp6$-C$ sb6$H$ sb6$)Cr(CO)$ sb2$(CS), Cr(CO)$ sb5$(CS), Re(CO)$ sb5$Cl, CH$ sb3$Re(CO)$ sb5$ and CH$ sb3$Mn(CO)$ sb5$ have been recorded under high pressures ($<$ 50kbar). Several phase transitions have been detected. The effects of pressure on the metal-ligand bonding interactions have been evaluated. The phase behaviour of C$ sb{60},$ K$ sb2$SnBr$ sb6$, K$ sb2$WO$ sb4$, K$ sb2$CrO$ sb4$ and Cs$ sb2$ (B$ sb{10}$Cl$ sb{10}$) has also been examined by high-pressure vibrational spectroscopy. / $ sp{13}$C chemical shift tensors and anisotropies have been obtained for $( eta sp6$-C$ sb6$H$ sb6$)Cr(CO)$ sb2$(CS), $( eta sp6$-C$ sb6$H$ sb6$)Cr(CO)$ sb3$, K (PtCl$ sb3( eta sp2$-C$ sb2$H$ sb4$)) and trans- (PtCl$ sb2( eta sp2$-C$ sb2$H$ sb4$)) $ sb2$. The CS ligand shielding ansiotropy is the largest ever observed for a $ sp{13}$C nucleus (530 ppm). $ sp{31}$P chemical shielding tensors have been determined for PPh$ sb3$, P(OPh)$ sb3, trans$-Cr(CO)$ sb4$(CS)(PPh$ sb3$) and trans-Cr(CO)$ sb3$(CS) (P(OPh)$ sb3$) $ sb2$. The results provide new insights into metal-phosphorus bonding interactions. / The molecular dynamics of the orientationally-disordered, cage hydrocarbons, 1-bromo- and 1-chloroadamantane, 1-adamantanecarboxylic acid and 2-adamantanone, have been investigated by $ sp{13}$C spin-lattice relaxation and dipolar dephasing time measurements. The motions in the disordered phases are different from those proposed on the basis of neutron scattering data. The phase behaviour of 1,3-dimethyladamantane has been studied by a combination of vibrational and proton NMR spectroscopy. The phase transitions in the cyclic hydrocarbons, cyclooctane, cyclooctanone and cyclohexanone, have been probed by vibrational spectroscopy. Unit cell symmetries have been proposed for all three compounds in their ordered phases. Cyclooctane and cyclooctanone form metastable phases. The different molecular motions in solid cyclohexanone have been established by $ sp2$H NMR lineshape analysis.
| Identifer | oai:union.ndltd.org:LACETR/oai:collectionscanada.gc.ca:QMM.39470 |
| Date | January 1992 |
| Creators | Huang, Yining |
| Publisher | McGill University |
| Source Sets | Library and Archives Canada ETDs Repository / Centre d'archives des thèses électroniques de Bibliothèque et Archives Canada |
| Language | English |
| Detected Language | English |
| Type | Electronic Thesis or Dissertation |
| Format | application/pdf |
| Coverage | Doctor of Philosophy (Department of Chemistry.) |
| Rights | All items in eScholarship@McGill are protected by copyright with all rights reserved unless otherwise indicated. |
| Relation | alephsysno: 001318467, proquestno: NN80508, Theses scanned by UMI/ProQuest. |
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