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toxicity identification evaluation of pore water from contaminated marine sediment =: 受污染的海洋底泥孔水之毒性鑑定評估研究. / 受污染的海洋底泥孔水之毒性鑑定評估研究 / The toxicity identification evaluation of pore water from contaminated marine sediment =: Shou wu ran de hai yang di ni kong shui zhi du xing jian ding ping gu yan jiu. / Shou wu ran de hai yang di ni kong shui zhi du xing jian ding ping gu yan jiu

by Kwok Yuk Chun. / Thesis (M.Phil.)--Chinese University of Hong Kong, 2004. / Includes bibliographical references (leaves 105-124). / Text in English; abstracts in English and Chinese. / by Kwok Yuk Chun. / Acknowledgements --- p.i / Abstract --- p.ii / Contents --- p.vi / List of Figures --- p.x / List of Tables --- p.xiii / List of Plates --- p.xiv / List of Appendices --- p.xv / Chapter 1. --- INTRODUCTION --- p.1 / Chapter 1.1 --- Hong Kong --- p.1 / Chapter 1.2 --- Sediment --- p.1 / Chapter 1.3 --- Pore water --- p.5 / Chapter 1.4 --- Toxicity identification evaluation (TIE) --- p.10 / Chapter 1.4.1 --- Phase 1: Toxicity characterization --- p.11 / Chapter 1.4.2 --- Phase 2: Toxicity identification --- p.11 / Chapter 1.4.3 --- Phase 3: Toxicity confirmation --- p.13 / Chapter 1.5 --- Bioassay --- p.15 / Chapter 1.6 --- Microtox® test --- p.16 / Chapter 2. --- OBJECTIVES --- p.18 / Chapter 3. --- MATERIALS AND METHODS --- p.19 / Chapter 3.1 --- Source of sediment samples --- p.19 / Chapter 3.2 --- Preparation of pore water --- p.19 / Chapter 3.3 --- Phase 1 Toxicity characterization: Baseline toxicity test --- p.22 / Chapter 3.3.1 --- Microtox® test --- p.22 / Chapter 3.3.2 --- Phase 1 Toxicity characterization --- p.26 / Chapter 3.3.3 --- pH adjustment test --- p.27 / Chapter 3.3.4 --- pH adjustment filtration test --- p.28 / Chapter 3.3.5 --- pH adjustment aeration test --- p.29 / Chapter 3.3.6 --- pH adjustment C18 solid phase extraction (SPE) test --- p.30 / Chapter 3.3.7 --- Cation exchange test --- p.32 / Chapter 3.3.8 --- Anion exchange test --- p.33 / Chapter 3.4 --- Phase 2 Toxicity identification --- p.34 / Chapter 3.4.1 --- Determination of metal ions by inductively coupled plasma emission spectroscopy (ICP-ES) --- p.35 / Chapter 3.4.2 --- Determination of anions by ion chromatography (IC) --- p.36 / Chapter 3.4.3 --- Determination of organic compounds by a total organic carbon (TOC) --- p.36 / Chapter 3.4.4 --- Determination of organic compounds by gas chromatography-mass spectroscopy (GC-MS) --- p.37 / Chapter 3.4.5 --- Determination of organic compounds by liquid chromatography-mass spectroscopy (LC-MS) --- p.38 / Chapter 3.4.6 --- Determination of sulphide by colorimetric method --- p.41 / Chapter 3.5 --- Phase 3 Toxicity confirmation --- p.41 / Chapter 3.5.1 --- Mass balance test --- p.44 / Chapter 3.5.2 --- Spiking test --- p.44 / Chapter 4. --- RESULTS --- p.45 / Chapter 4.1 --- General characteristics of the sediment collected in Kwun Tong Typhoon Shelter --- p.45 / Chapter 4.2 --- General characteristics of the pore water after the centrifugation of sediment --- p.45 / Chapter 4.3 --- Phase 1-Toxicity characterization: Baseline toxicity test --- p.45 / Chapter 4.4 --- Phase 1-Toxicity characterization --- p.48 / Chapter 4.4.1 --- Effect of manipulations on Sample S1 --- p.48 / Chapter 4.4.2 --- Effect of manipulations on Sample S2 --- p.50 / Chapter 4.4.3 --- Effect of manipulations on Sample S3 --- p.50 / Chapter 4.4.4 --- Effect of manipulations on Sample S4 --- p.52 / Chapter 4.4.5 --- Effect of manipulations on Sample S5 --- p.55 / Chapter 4.4.6 --- Effect of manipulations on Sample S6 --- p.57 / Chapter 4.4.7 --- Summary of the Phase 1 manipulations on the Microtox® test --- p.59 / Chapter 4.5 --- Phase 2-Toxicity identification --- p.59 / Chapter 4.5.1 --- Summary of the Phase 2 toxicity identification --- p.70 / Chapter 4.6 --- Phase 3-Toxicity confirmation --- p.70 / Chapter 4.6.1 --- Result of Phase 3 for Sample S3 --- p.70 / Chapter 4.6.2 --- Result of Phase 3 for Sample S4 --- p.73 / Chapter 4.6.3 --- Result of Phase 3 for Sample S5 --- p.76 / Chapter 4.6.4 --- Result of Phase 3 for Sample S6 --- p.79 / Chapter 4.6.5 --- Summary of the Phase 3 toxicity confirmation --- p.79 / Chapter 5. --- DISCUSSION --- p.82 / Chapter 5.1 --- Phase 1 Toxicity characterization: Baseline toxicity test --- p.82 / Chapter 5.1.1 --- Baseline toxicity of whole pore water samples on the Microtox® test --- p.82 / Chapter 5.2 --- Phase 1-Toxicity characterization: Manipulations --- p.83 / Chapter 5.2.1 --- Effect of manipulations on the Microtox® test --- p.83 / Chapter 5.2.2 --- pH adjustment test --- p.83 / Chapter 5.2.3 --- pH adjustment filtration test --- p.84 / Chapter 5.2.4 --- pH adjustment aeration test --- p.85 / Chapter 5.2.5 --- Cation exchange test --- p.85 / Chapter 5.2.6 --- Anion exchange test --- p.86 / Chapter 5.2.7 --- pH adjustment C18 solid phase extraction (SPE) test --- p.86 / Chapter 5.3 --- Phase 2-Toxicity identification --- p.87 / Chapter 5.4 --- Phase 3-Toxicity confirmation --- p.88 / Chapter 5.4.1 --- Mass balance on the Microtox® test --- p.89 / Chapter 5.4.2 --- Spiking test on the Microtox® test --- p.90 / Chapter 5.5 --- Explanation of S as the major toxicant in Phase 1,Phase 2 and Phase3 --- p.90 / Chapter 5.6 --- Characteristics of Sulphide (S2-) --- p.91 / Chapter 5.6.1 --- Sources of S2- --- p.91 / Chapter 5.6.2 --- Harmful effect of S “ and its toxicity --- p.93 / Chapter 5.6.3 --- Sulphide determination by colorimetric method --- p.94 / Chapter 5.6.4 --- Sulphide determination by other methods --- p.95 / Chapter 5.6.5 --- Sulphide preservation --- p.95 / Chapter 5.7 --- Synergistic effect of S2- and C18 SPE test elutriate --- p.96 / Chapter 5.8 --- Treatment of contaminated marine sediment in Hong Kong --- p.97 / Chapter 5.9 --- Treatment of contaminated marine sediment in Kwun Tong Typhoon Shelter --- p.98 / Chapter 5.10 --- Treatment of sediment contaminated with sulphide in Hong Kong --- p.99 / Chapter 5.11 --- Other treatment method of sediment contaminated with sulphide --- p.100 / Chapter 5.12 --- Current limitations and abilities in identification of toxicants in pore water --- p.101 / Chapter 5.13 --- Improvement and Recommendations --- p.102 / Chapter 6. --- CONCLUSIONS --- p.104 / Chapter 7. --- REFERENCES --- p.105 / Chapter 8. --- APPENDICES --- p.125

Identiferoai:union.ndltd.org:cuhk.edu.hk/oai:cuhk-dr:cuhk_324596
Date January 2004
ContributorsKwok, Yuk Chun., Chinese University of Hong Kong Graduate School. Division of Biology.
Source SetsThe Chinese University of Hong Kong
LanguageEnglish, Chinese
Detected LanguageEnglish
TypeText, bibliography
Formatprint, xvi, 137 leaves : ill., maps (1 col.) ; 30 cm.
CoverageChina, Hong Kong, China, Hong Kong
RightsUse of this resource is governed by the terms and conditions of the Creative Commons “Attribution-NonCommercial-NoDerivatives 4.0 International” License (http://creativecommons.org/licenses/by-nc-nd/4.0/)

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