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Copolymerizing Acrylonitrile and Methyl Acrylate by RAFT for Melt Processing Applications: A Synthetic Investigation of the Effects of Chain Transfer Agent, Initiator, Temperature, and Solvent

Statistical copolymers of acrylonitrile (AN) and methyl acrylate (MA) were successfully prepared and characterized using reversible addition-fragmentation chain transfer (RAFT) copolymerization. A typical copolymer was charged with 15 wt. % MA content. This thesis describes a systematic variation of the RAFT copolymerization variables to optimize this system. In particular, the effects of chain transfer agent, initiator, temperature, and solvent on the copolymer properties were studied. / Master of Science

Identiferoai:union.ndltd.org:VTETD/oai:vtechworks.lib.vt.edu:10919/49104
Date23 June 2014
CreatorsBeck, Susan Ashley
ContributorsMacromolecular Science and Engineering, Turner, S. Richard, Mecham, Beverly S., Riffle, Judy S., Moore, Robert Bowen, Baird, Donald G.
PublisherVirginia Tech
Source SetsVirginia Tech Theses and Dissertation
Detected LanguageEnglish
TypeThesis
FormatETD, application/pdf, application/pdf
RightsIn Copyright, http://rightsstatements.org/vocab/InC/1.0/

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