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Ultra-large sheet formation by 1D to 2D hierarchical self-assembly of a “rod–coil” graft copolymer with a polyphenylene backbone

This communication reports a unique ultra-large sheet formation through hierarchical self-assembly of a rod–coil graft copolymer containing a rigid polyphenylene backbone and flexible poly(ethylene oxide) (PEO) side chains. The hierarchical self-assembly process involved a distinctive morphological transition of 1D helical to 2D superstructures. The graft copolymer offers a new chance for the challenging bottom-up fabrication of ultra-large self-assembled nanosheets in solution, as well as a novel system for fundamental studies on 2D self-assembly of polymers.

Identiferoai:union.ndltd.org:DRESDEN/oai:qucosa.de:bsz:14-qucosa-225638
Date17 July 2017
CreatorsHuang, Yinjuan, Yuan, Rui, Xu, Fugui, Mai, Yiyong, Feng, Xinliang, Yan , Deyue
ContributorsRoyal Society of Chemistry,
PublisherSaechsische Landesbibliothek- Staats- und Universitaetsbibliothek Dresden
Source SetsHochschulschriftenserver (HSSS) der SLUB Dresden
LanguageEnglish
Detected LanguageEnglish
Typedoc-type:article
Formatapplication/pdf
SourcePolymer Chemistry (2016), 7(6). S. 1234-1238. ISSN: 1759-9962. DOI: 10.1039/C5PY01969A.

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