Motorboat activity can adversely effect the water quality of a reservoir. The potential impacts of motorboat activity on the Occoquan Reservoir's water and sediments were evaluated. Thirty-one sites, both marina and nonmarina, along the reservoir were selected. Sediment and water samples were collected in 1990, during peak boating activity, and in October, during low boating activity. The objectives of this research were to determine the concentrations of polyaromatic hydrocarbons (PAHs) in water and sediment samples and to determine if their presence was related to boating activity. The presence of other non-PAH organics was also determined. Contours of total PAH concentrations, boxplots and ANOVA analyses between marina and nonmarina sites were generated from gathered data in order to meet these objectives.
PAHs were present in the water during peak boating activity and not detected during low boating activity, while PAHS were detected in the sediments during both sampling periods. The aqueous and sediment PAH concentrations were at or below the method detection limits. The PAH ratios of unalkylated PAHs confirmed PAH contamination to be of a combustion source. Boating was shown to be a PAH source to the water column, during peak boating activity, throughout the entire Occoquan Reservoir. An ANOVA between marina and nonmarina sites for the aqueous total PAH concentrations did not show a significant difference in June. This implied that boating did not cause any localized impacts to the water column and that there was another PAH source. There was a significant difference for total PAH concentrations between the marina and nonmarina sites for the sediment samples in June, showing localized impacts at marina areas due to boating activity. PAH profiles showed urban runoff as another major contributor to the PAH concentration in the water and sediments. The urbanization of Hooes Run and the hydrology of the reservoir caused urban runoff to impact localized areas. Finally, atmospheric deposition was also a source of PAHs to the sediments throughout the entire reservoir.
Non-PAH organics found in a few of the water and sediment samples were the pesticides atrazine and p,p'-DDD, alkyl phosphates, alcohols and Cā to Cāā hydrocarbons. / Master of Science
| Identifer | oai:union.ndltd.org:VTETD/oai:vtechworks.lib.vt.edu:10919/44395 |
| Date | 22 August 2009 |
| Creators | Mastran, Trina Ann |
| Contributors | Environmental Engineering |
| Publisher | Virginia Tech |
| Source Sets | Virginia Tech Theses and Dissertation |
| Language | English |
| Detected Language | English |
| Type | Thesis, Text |
| Format | xx, 230 leaves, BTD, application/pdf, application/pdf |
| Rights | In Copyright, http://rightsstatements.org/vocab/InC/1.0/ |
| Relation | OCLC# 26088321, LD5655.V855_1992.M379.pdf |
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