The aim of this study was to develop a new single-part healing system for self-healing composites. The self-healing approach to composite repair has been developed in the last two decades and means that a damaged area can be repaired by material already housed within the structure. The background and development of self-healing has been reviewed. The two main self-healing mechanisms are discussed. To date only two part self healing systems have been examined. These require diffusion of the separate constituents to a single location in order to effect cure and restore strength. Single part adhesives do not have this disadvantage and are therefore very attractive. Several candidate single-part adhesive or resin systems were considered and discussed according to the critical requirements of a self-healing system. A series of experiments was undertaken to evaluate the possibility of candidate adhesive systems being effective for self-healing by focusing on the determination of storage stability and bonding efficiency. The results of storage stability testing showed that the stability of cyanoacrylate and polyurethane adhesives was poor. However silane and polystyrene cements showed good storage stability. Very low bonding efficiency was achieved with polystyrene cement but a 22% strength recovery was obtained with the silane 3-[tris(trimethylsiloxy)silyl]-propylamine. Suggestions for further research into single-part healing systems are also given.
| Identifer | oai:union.ndltd.org:ADTP/257597 |
| Date | January 2007 |
| Creators | Wang, Xufeng, Materials Science & Engineering, Faculty of Science, UNSW |
| Publisher | Awarded by:University of New South Wales. Materials Science and Engineering |
| Source Sets | Australiasian Digital Theses Program |
| Language | English |
| Detected Language | English |
| Rights | Copyright Xufeng Wang, http://unsworks.unsw.edu.au/copyright |
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