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Polynuclear complexes as precursor templates for hierarchical microporous graphitic carbon: An unusual approach

Yes / A highly porous carbon was synthesized using a coordination complex as an unusual precursor. During controlled pyrolysis, a trinuclear copper complex, [CuII3Cl4(H2L)2]·CH3OH, undergoes phase changes with melt and expulsion of different gases to produce a unique morphology of copper-doped carbon which, upon acid treatment, produces highly porous graphitic carbon with a surface area of 857 m2 g–1 and a gravimetric hydrogen uptake of 1.1 wt % at 0.5 bar pressure at 77 K. / EPSRC (EP/R01650X/1 for VPT, and EP/E040071/1 for MT) and the University of Bristol

Identiferoai:union.ndltd.org:BRADFORD/oai:bradscholars.brad.ac.uk:10454/16535
Date17 July 2018
CreatorsKobielska, Paulina A., Telford, Richard, Rowlandson, J., Tian, M., Shahin, Z., Demessence, A., Ting, V.P., Nayak, Sanjit
Source SetsBradford Scholars
LanguageEnglish
Detected LanguageEnglish
TypeArticle, Accepted manuscript
RightsThis document is the Accepted Manuscript version of a Published Work that appeared in final form in ACS Applied Materials & Interfaces, copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see http://dx.doi.org/10.1021/acsami.8b10149, Unspecified

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