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Solution-processed Schottky-quantum Dot Photovoltaics for Efficient Infrared Power Conversion

Solar energy harvesting demands low-cost energy conversion in the infrared from 1 – 2 μm. However, solution-processed photovoltaic devices have remained relatively inefficient in this spectral region. Herein, lead sulfide colloidal nanocrystal quantum dots are used to facilitate efficient infrared power conversion. Solution-cast nanocrystal films are employed in a simple metal/semiconductor/metal architecture to produce a photovoltaic effect. It is shown that a Schottky barrier is induced, which is responsible for the charge separating action. Through optimization of chemical processes and device fabrication, the photovoltaic response is maximized. The infrared power conversion efficiency reaches 4.2%, which sets a new precedent for solution-processed photovoltaic cells. Furthermore, the devices exhibit efficient broadband solar power conversion and show promise for multijunction cell architectures. Carrier drift through a large depletion region near the Schottky contact is determined to be the dominant transport mechanism.

Identiferoai:union.ndltd.org:LACETR/oai:collectionscanada.gc.ca:OTU.1807/11145
Date30 July 2008
CreatorsJohnston, Keith
ContributorsSargent, Ted
Source SetsLibrary and Archives Canada ETDs Repository / Centre d'archives des thèses électroniques de Bibliothèque et Archives Canada
Languageen_ca
Detected LanguageEnglish
TypeThesis
Format2272941 bytes, application/pdf

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