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Part I¡GApplication of Electroorganic Chemistry toward the Synthesis of Tropane Alkaloids Part II¡GSyntheses of Aporphine Alkaloids via Radical Cyclization Reactions

Part I: Pyrrolidine derivatives were attached a methoxy group on a-C position of pyrrolidine-ring via anodic oxidation. Followed with alkylation and series of transformation under Lewis acids to obtain tropane alkaloids.
Part II: Application of intramolecular radical cyclization toward the synthesis of aporphine alkaloids. Tributyltinhydride and AIBN were used to generate aryl radicals. Trapping of aryl radicals with unsaturated alkenes led to products.

Identiferoai:union.ndltd.org:NSYSU/oai:NSYSU:etd-0707100-112135
Date07 July 2000
CreatorsChou, Wu-Sen
ContributorsChi-Wi Ong, Chih-Shone Lee, Chin-Hsing Chou
PublisherNSYSU
Source SetsNSYSU Electronic Thesis and Dissertation Archive
LanguageCholon
Detected LanguageEnglish
Typetext
Formatapplication/pdf
Sourcehttp://etd.lib.nsysu.edu.tw/ETD-db/ETD-search/view_etd?URN=etd-0707100-112135
Rightsnot_available, Copyright information available at source archive

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