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Diffusion in Metals and Intermetallics: an Overview

After a few remarks about the history of diffusion in solids we remind
the reader to some basics of diffusion such as tracer diffusion, interdiffusion, high-
diffusivity paths, and basic diffusion mechanism in solids. We then summarize
self-diffusion in cubic, hexagonal metals and metals with phase transformations.
Then we summarize diffusion of substitutional impurities (solutes) in metals and
remind the reader to the phenomena of slow solute diffusion in aluminium and of
fast solute diffusion in polyvalent metals. We finish the part on solute diffusion
with some remarks on interstitial impurities We start the part on intermetallic
alloys by reminding the reader to some of the more frequent structures. We
consider examples of the influence of order-disorder transformation on diffusion.
We then discuss diffusion in cubic B2-structured phases and in B2-, L12 - and DO 3-
intermetallics, We then discuss uniaxial L1 0 -intermetallics and C11 b-structured
molybdenum disilicide. We finish with some remarks diffusion in the cubic Laves
phase Co2 Nb.:1. Introduction – some historical remarks
2. Some basics
2.1 Tracer diffusion
2.2 Interdiffusion
2.2.2 The ‘random alloy’ approximation for interdiffusion
2.2.1 Boltzmann-Matano method
2.3 High-diffusivity paths in solids
2.4 Diffusion mechanisms in solids
3. Self-diffusion in metals
3.1 Cubic metals
3.2 Uniaxial metals
3.3 Metals with phase transitions
4, Impurity diffusion in metals
4.1 Diffusion of substitutional impurities
4.2 Slow impurity diffusion in aluminium
4.3 Fast impurity diffusion in polyvalent metals
4.4 Diffusion of fast diffusing interstitial impurities and of hydrogen
5. Diffusion in Intermetallics
5.1 Some structures of intermetallics
5.2 Influence of order-disorder transitions on diffusionThis work is licensed under a Creative Commons Attribution 4.0 International License.
To view a copy of this license, visit http://creativecommons.org/licenses/by/4.0/1
5.3 Diffusion in B2 phases and B2-intermetallics
5.4 Diffusion in L12-intermetallics
5.5 Diffusion in DO3-intermetallics
5.5 Diffusion in L10-intermetallics
5.6 Diffusion in C11b-structured molybdenum disilicide
5.6 Diffusion in the Laves phase Co 2Nb

Identiferoai:union.ndltd.org:DRESDEN/oai:qucosa:de:qucosa:80742
Date21 September 2022
CreatorsMehrer, Helmut
PublisherUniversity of Leipzig
Source SetsHochschulschriftenserver (HSSS) der SLUB Dresden
LanguageEnglish
Detected LanguageEnglish
Typeinfo:eu-repo/semantics/publishedVersion, doc-type:article, info:eu-repo/semantics/article, doc-type:Text
Rightsinfo:eu-repo/semantics/openAccess
Relation1862-4138, urn:nbn:de:bsz:15-qucosa2-806868, 02, qucosa:80686

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