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Previous issue date: 2015-06-05 / Coordena??o de Aperfei?oamento de Pessoal de N?vel Superior (CAPES) / A estocagem de rejeitos de scheelita a ?c?u aberto? resultante da explora??o da mina Breju? da regi?o de Currais Novos, Rio Grande do Norte, Brasil, tem gerado, no per?odo 1960-2015, um forte passivo ambiental. O pol?mero politetrafluoretileno (PTFE) majora em sistemas de deslizamento e reduz significativamente custos de manuten??o, devido ?s suas excelentes propriedades mec?nicas, tais como baixo coeficiente de atrito (0,01< m <0,10) e limite de escoamento da ordem de 10 MPa. No entanto, apresenta elevadas taxas de desgaste (10-13 m2/N) e por despertar o interesse cient?fico e tecnol?gico nas ind?strias petroqu?mica e aeroespacial na forma de lubrificantes s?lidos, objetivou-se desenvolver comp?sitos polim?ricos com matriz de PTFE utilizando-se o rejeito de scheelita como carga, viabilizando tamb?m processos de remedia??o ambiental. O Rejeito de Scheelita foi caracterizado na condi??o como adquirido, atrav?s de an?lises de DRX, FRX, MEV, EDS, granulometria por Peneiramento e a Laser, registrando-se tra?os de tungst?nio e metais estrat?gicos igualmente importantes. O PTFE foi analisado por TGA, DSC, MEV, DRX, FRX. Para o desenvolvimento dos comp?sitos misturou-se mecanicamente os p?s de PTFE e Rejeito de Scheelita, devidamente preparados e pesados. Para moldagem por compress?o ? quente projetou-se um molde cil?ndrico de a?o acoplado a uma resist?ncia inseridos numa prensa hidr?ulica. Avaliaram-se o desempenho tribol?gico dos comp?sitos obtidos a partir de Rugosidade, Dureza, Molhabilidade, Absor??o ao impacto, Esclerometria, Pino Disco e Analise Morfol?gica. Os resultados indicam que a varia??o no teor de rejeito de scheelita influ?ncia nos resultados de rugosidade, dureza e absor??o ao impacto. Comp?sitos molhados com ?gua salina e destilada caracterizaram-se como hidrof?bicos, enquanto que os molhados com ?leo paraf?nico e naft?nico como oleof?licos. Correlacionando os resultados dos ensaios tribol?gicos e custos constatou-se que a composi??o de 20% de Rejeito de Scheelita apresentou a melhor planicidade, baixo consumo de energia de deforma??o espec?ficica (<0,30 J/mm3), a menor perda m?ssica (8x10-3g) e afundamento da pista (<0,4 ?m/km). / The storage scheelite tailings in the open air as a result of Breju? mine exploration, located near Currais Novos, Rio Grande do Norte, Brazil, between 1960 and 2015, a strong environmental passive. The polymer polytetrafluoroethylene (PTFE) outstands in sliding systems and significantly reduces maintenance costs, due to its excellent mechanical properties, such as low friction coefficient (0,01< ? <0,10) and yield limit to the order of 10MPa. However, it has high wear rates (10-13 m2/N) and for arousing scientific and technological interests at petrochemical and aerospace industry, in the form of solid lubricants, the target was to develop polymeric composites with a PTFE matrix using tailings of scheelite as charge, enabling also environmental remediation processes. The tailing of Sheelite was characterized in acquired conditions, through XRD, XRF, SEM, EDS, granulometry by screening and by laser, recording traces of tungsten and strategic metals equally important. The PTFE was analyzed by TG, DSC, SEM, XRD, XRF. To the composites development, powders of PTFE and tailings of sheelite were mechanically mixed, previously prepared and weighed. To hot compression molding, a designed cylindrical steel mould was coupled with a resistor and placed in a hydraulic press. The composite?s tribological performance was evaluated from roughness, hardness, wettability, impact absorption, sclerometry, pin on disc, and morphological analysis. The results show that the variation in the tailing of scheelite concentration influences the results of roughness, hardness and impact absorption. Wet composites with saline and distilled water were characterized as hydrophobic, and the ones wet with paraffenic and naphtenic oil, they acted oleophilic. Correlating the results of tribological tests and costs, it was found that the composition of 20% mineral filler showed better planeness, low specific deformation energy consumption (<0,30J/mm?), the lowest mass loss (8x10-4g) and trail shipwreck (<0,4?m/km).
| Identifer | oai:union.ndltd.org:IBICT/oai:repositorio.ufrn.br:123456789/20564 |
| Date | 05 June 2015 |
| Creators | Souza, Juliana Ricardo de |
| Contributors | 10973370491, http://lattes.cnpq.br/3206952338356447, Silva, Ademir Oliveira da, 16225422404, http://lattes.cnpq.br/3511004608337461, Santos, Am?lia Severino Ferreira e, 59284064104, http://lattes.cnpq.br/5119417295487126, Cavalcante, Danielle Guedes de Lima, 01027266479, http://lattes.cnpq.br/2575577028682912, Melo, Mois?s Vieira de, 10774556404, http://lattes.cnpq.br/1337846419129004, Matamoros, Efrain Pantaleon, Medeiros, Jo?o Telesforo N?brega de |
| Publisher | Universidade Federal do Rio Grande do Norte, PROGRAMA DE P?S-GRADUA??O EM ENGENHARIA MEC?NICA, UFRN, Brasil |
| Source Sets | IBICT Brazilian ETDs |
| Language | Portuguese |
| Detected Language | English |
| Type | info:eu-repo/semantics/publishedVersion, info:eu-repo/semantics/doctoralThesis |
| Source | reponame:Repositório Institucional da UFRN, instname:Universidade Federal do Rio Grande do Norte, instacron:UFRN |
| Rights | info:eu-repo/semantics/openAccess |
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