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Synthesis and Characterization of Zinc Thiosalen Derived Complexes

In this study, we took four diamines of different carbon chain lengthes to synthesize several thiosalen derived zinc(II) complexes, i.e. N, N¡¦-Bis- (2-thio-benzylidene)- 1,3-propylenediaminato-zinc(II)(1),N,N¡¦-Bis(2-thio-benzylidene)-2,2-dimethyl- 1,3-propylenediaminato-zinc(II)(2),N,N¡¦-Bis-(2-thio-benzylidene)-1,2-ethylene- diaminato-zinc(II)(3),andN,N¡¦-Bis(2-thio-benzylidene)-1-methyl-1,2-ethylene- diaminato-zinc(II)(4). The crystal structure of 1 was shown to be trimeric. We then used NaBH4 to reduced complexes1, 2, and 4 to get complexes 5, 6, and 7 respectively for reactivity and structure studies. To expand our current study, we also synthesized nickel analogue (8) of complex 1 by transmetallation.

Identiferoai:union.ndltd.org:NSYSU/oai:NSYSU:etd-0717112-212228
Date17 July 2012
CreatorsLin, Chia-hui
ContributorsTsu-hsin Chang, Michael Yen-nan Chiang, Chih-neng Hsu
PublisherNSYSU
Source SetsNSYSU Electronic Thesis and Dissertation Archive
LanguageCholon
Detected LanguageEnglish
Typetext
Formatapplication/pdf
Sourcehttp://etd.lib.nsysu.edu.tw/ETD-db/ETD-search/view_etd?URN=etd-0717112-212228
Rightsunrestricted, Copyright information available at source archive

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