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Application of a chiral metal–organic framework in enantioselective separation

A modular approach for the synthesis of highly ordered porous and chiral auxiliary (Evans auxiliary) decorated metal–organic frameworks is developed. Our synthesis strategy, which uses known porous structures as model materials for incorporation of chirality via linker modification, can provide access to a wide range of porous materials suitable for enantioselective separation and catalysis. Chiral analogues of UMCM-1 have been synthesized and investigated for the enantioseparation of chiral compounds in the liquid phase and first promising results are reported. / Dieser Beitrag ist mit Zustimmung des Rechteinhabers aufgrund einer (DFG-geförderten) Allianz- bzw. Nationallizenz frei zugänglich.

Identiferoai:union.ndltd.org:DRESDEN/oai:qucosa.de:bsz:14-qucosa-138682
Date31 March 2014
CreatorsPadmanaban, Mohan, Müller, Philipp, Lieder, Christian, Gedrich, Kristina, Grünker, Ronny, Bon, Volodymyr, Senkovska, Irena, Baumgärtner, Sandra, Opelt, Sabine, Paasch, Silvia, Brunner, Eike, Glorius, Frank, Klemm, Elias, Kaskel, Stefan
ContributorsRoyal Society of Chemistry,
PublisherSaechsische Landesbibliothek- Staats- und Universitaetsbibliothek Dresden
Source SetsHochschulschriftenserver (HSSS) der SLUB Dresden
LanguageEnglish
Detected LanguageEnglish
Typedoc-type:article
Formatapplication/pdf
SourceChemical Communications 2011;47:12089–12091, ISSN: 1359-7345

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