The objective of my MSc thesis is to study the self-assembly process of macrocyclic complexes, as well as the properties that affect the obtained supramolecular architectures. The possibility of substrate recognition within the cavity of these complexes is also of interest. Preparation of three new ligands based on the triazole-pyridine chelating units connected through variable spacer groups, as well as the complexes formed with octahedral metal ions, are described herein.
The first ligand contained a naphthalene spacer region, which was longer than the previously examined xylene spacer. This extension increases the distance between metal ions in the complex, as well as the size of the cavity. More work is required to obtain the unsaturated double-stranded complex, which could potentially bind substrate molecules within its cavity. The triple-stranded saturated complexes with [Fe(H2O)6](BF4)2 and [Ni(H2O)6](BF4)2 both gave insight into the process of self-assembly.
The next two ligands were designed to probe the effect that increasing the length of an aliphatic spacer had on complex self-assembly. Both ethyl and propyl spacer units had been previously studied, so butyl and pentyl spacer groups were the natural next step to analyze. The length of the alkyl spacer was found to be very important in the nature of the obtained complex. As the length of the alkyl chain, and the corresponding flexibility increased, so too did the complexity of the resulting supramolecular architectures. / Thesis (Master, Chemistry) -- Queen's University, 2013-09-03 12:21:39.581
| Identifer | oai:union.ndltd.org:LACETR/oai:collectionscanada.gc.ca:OKQ.1974/8247 |
| Date | 03 September 2013 |
| Creators | Stevenson, Kristina |
| Contributors | Queen's University (Kingston, Ont.). Theses (Queen's University (Kingston, Ont.)) |
| Source Sets | Library and Archives Canada ETDs Repository / Centre d'archives des thèses électroniques de Bibliothèque et Archives Canada |
| Language | English, English |
| Detected Language | English |
| Type | Thesis |
| Rights | This publication is made available by the authority of the copyright owner solely for the purpose of private study and research and may not be copied or reproduced except as permitted by the copyright laws without written authority from the copyright owner. |
| Relation | Canadian theses |
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