Martensite-to-Beta transformation temperatures of CuAlNiMn and CuAlNi shape memory alloys has been determined by differential scanning calorimetry (DSC). In CuAlNiMn alloys, each new betatizing treatment has resulted in randomly varying transformation temperatures on the same specimen and an anomalously diffuse and serrated Martensite-to-Beta transformation peaks in the first cycle. Therefore, as quenched alloy samples were thermally cycled for three times in DSC prior to ageing to obtain thermally stable and reproducible transformation temperatures and to eliminate the anomalous effect of betatizing on the transformation temperatures.
CuAlNiMn alloys were aged in martensitic condition at temperatures in the range 80& / #61616 / C to 150& / #61616 / C for 24 hours to 312 hours ageing periods. Both A_s and A_f temperatures have increased with ageing temperature and time while M_s and M_f temperatures have not changed during martensite ageing. Transformation temperatures of CuAlNi alloys, on the other hand, have not changed during martensite ageing. In this respect, CuAlNiMn alloys were found to be more prone to martensite stabilization than the CuAlNi alloys. Through Transmission Electron Microscope investigation in the Cu-12.6wt%Al-5.9wt%Ni-1.8wt%Mn alloy aged at 150& / #61616 / C for 312 hours has revealed no sign of precipitate formation and it has been concluded that the & / #65533 / precipitates pinning martensite boundaries& / #65533 / mechanism could not be responsible of martensite stabilization.
Beta phase ageing of CuAlNiMn alloys at temperatures 200& / #61616 / C, 230& / #61616 / C, 250& / #61616 / C and 270& / #61616 / C, have drastically shortened the periods for stabilization to the extent that & / #946 / -to-M transformation completely ceases. With regard to the Manganese content, highest Manganese bearing alloy was the one stabilized first and the lowest manganese containing one was the longest lasting alloy during beta phase ageing. Beta stabilization was not observed in any of the four CuAlNi alloys at the end of 96 hours ageing at 200& / #61616 / C while beta stabilization was realized after 26, 38 and 11 hours ageing at the same temperature in the three Mn containing alloys studied. In conclusion, on the basis of ageing studies at 200& / #61616 / C, with regard to beta stabilization, CuAlNi alloys were found to be more resistant to high temperature ageing than CuAlNiMn alloys.
Equilibrium & / #947 / _2 and & / #945 / phases were observed with coupled-grown lamellar morphologies in Cu-13.6%Al-3.0%Ni alloy aged above 400& / #61616 / C.
| Identifer | oai:union.ndltd.org:METU/oai:etd.lib.metu.edu.tr:http://etd.lib.metu.edu.tr/upload/3/593541/index.pdf |
| Date | 01 January 2004 |
| Creators | Tarhan, Elif - |
| Contributors | Bor, Sakir Ali |
| Publisher | METU |
| Source Sets | Middle East Technical Univ. |
| Language | English |
| Detected Language | English |
| Type | Ph.D. Thesis |
| Format | text/pdf |
| Rights | To liberate the content for public access |
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