Mesoporous silica gel was functionalized by various organic functional groups using thiol-ene coupling of surface thiol groups with 4-vinylphenylboronic acid followed by Suzuki coupling with aromatic halides. For better performance, the synthesis was conducted under sonication. The presence of surface functional groups was confirmed by thermoanalysis, FT-IR spectroscopy and characteristic reactions of these groups. Solid-phase conditions of the synthesis eliminate the risk of side reactions of boronic acids.
| Identifer | oai:union.ndltd.org:ETSU/oai:dc.etsu.edu:etsu-works-11189 |
| Date | 12 September 2019 |
| Creators | Kuvayskaya, Anastasia, Vasiliev, Aleksey |
| Publisher | Digital Commons @ East Tennessee State University |
| Source Sets | East Tennessee State University |
| Detected Language | English |
| Type | text |
| Source | ETSU Faculty Works |
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