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Impurities and the Evaporation Morphology of Zinc Single Crystals

<p> In this thesis the results of optical and scanning electron
microscopic investigations of the evaporation morphology of zinc single crystals are presented. Dislocation etch pits developed on (0001) zinc cleavage surfaces. A mechanism is proposed to account for enhanced evaporation at decorated dislocations. The observation of macroledges on pit faces is reported and attributed to impurity-induced bunching of monatomic ledges, the impurities having out-diffused from the bulk. A proposed model for evaporation of faceted surfaces is used to interpret the ledge morphology which developed when samples were evaporated in an oxygen environment. Finally, a correlation between the effects of bulk impurities and gaseous impurities on ledge morphology is demonstrated.</p> / Thesis / Doctor of Philosophy (PhD)

Identiferoai:union.ndltd.org:mcmaster.ca/oai:macsphere.mcmaster.ca:11375/17180
Date January 1970
CreatorsCarson, William Alfred John
ContributorsIves, M.B., Physics
Source SetsMcMaster University
LanguageEnglish
Detected LanguageEnglish
TypeThesis

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