The diploma thesis deals with preparation of acrylic copolymers via emulsion polymerization technique. Two sets of copolymer samples were prepared within this thesis, n BA/MMA and 2-EHA/MMA copolymers. n-BA/MMA copolymer sample was used for investigation of effect of surfactant concentration as well as effect of addition of acrylic acid to the feed composition. During all the copolymerizations, conversion was observed via solids content evaluation as the reaction progressed. Copolymerization was lead under inert atmosphere at continuous stirring and 80 °C for 4 hours. Glass transition temperature of samples was determined with DSC and Vicat softening point was measured as well. Data acquired from measurements were compared with values calculated with Fox equation which was used for modelling molar ratio of monomers in initial feed.
| Identifer | oai:union.ndltd.org:nusl.cz/oai:invenio.nusl.cz:216911 |
| Date | January 2013 |
| Creators | Arvai, Tomáš |
| Contributors | Petrůj, Jaroslav, Kučera, František |
| Publisher | Vysoké učení technické v Brně. Fakulta chemická |
| Source Sets | Czech ETDs |
| Language | Czech |
| Detected Language | English |
| Type | info:eu-repo/semantics/masterThesis |
| Rights | info:eu-repo/semantics/restrictedAccess |
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