Chiral recognition in metal–organic frameworks studied by solid-state NMR spectroscopy using chiral solvating agents

Description

Recently, we have described the synthesis of chiral metal–organic frameworks iPr-ChirUMCM-1 and Bn-ChirUMCM-1 and their use in enantioselective separation. Here, we demonstrate for the first time the use of a chiral solvating agent (1-phenyl-2,2,2-trifluoroethanol, TFPE) for chiral recognition in iPr-ChirUMCM-1 and Bn-ChirUMCM-1 by means of solid-state13C NMR spectroscopy. / Dieser Beitrag ist mit Zustimmung des Rechteinhabers aufgrund einer (DFG-geförderten) Allianz- bzw. Nationallizenz frei zugänglich.

Links & Downloads

1. urn:nbn:de:bsz:14-qucosa-138884
2. 404978754
3. https://tud.qucosa.de/id/qucosa%3A27789
4. https://tud.qucosa.de/api/qucosa%3A27789/attachment/ATT-0/

Tags

info:eu-repo/classification/ddc/540

ddc:540

Additional Fields

Identifer	oai:union.ndltd.org:DRESDEN/oai:qucosa:de:qucosa:27789
Date	January 2012
Creators	Hoffmann, Herbert C., Paasch, Silvia, Müller, Philipp, Senkovska, Irena, Padmanaban, Mohan, Glorius, Frank, Kaskel, Stefan, Brunner, Eike
Publisher	Royal Society of Chemistry
Source Sets	Hochschulschriftenserver (HSSS) der SLUB Dresden
Language	English
Detected Language	English
Type	doc-type:article, info:eu-repo/semantics/article, doc-type:Text
Source	Chemical communications 2012;48:10484-10486, ISSN: 1359-7345
Rights	info:eu-repo/semantics/openAccess
Relation	10.1039/c2cc35366k