Y2O3:Eu particles are phosphors that have found wide applications. Flamesynthesized
Y2O3:Eu particles may have either the cubic or the monoclinic structure. The
effects of particle size and Eu doping concentration on crystal structure and the surface
elemental composition of the flame-synthesized Y2O3:Eu particles had not been
previously reported.
In this study, a flame aerosol process was used to generate polydisperse Y2O3:Eu
particle. H2 was used as the fuel gas, with either air or O2 gas as the oxidizer. The
precursor was aqueous solutions of the metal nitrates, atomized using a 1.7-MHz
ultrasonic atomizer. The product particles were analyzed by transmission electron
microscopy (TEM), X-ray diffractometer (XRD), Selected area electron diffraction
(SAED), X-ray photoelectron spectroscopy (XPS), fluorescence spectrophotometer, and
inductively coupled plasma mass spectrometer (ICP-MS).
The Y2O3:Eu particles generated in H2/O2 flames were spherical and fully dense,
with diameters in the range of 10~3000 nm. In particle samples with lower Eu doping
concentrations, a critical particle diameter was found, whose value increased with increasing Eu doping concentration. Particles well below the critical diameter had the
monoclinic structure; those well above the critical diameter had the cubic structure. At
sufficiently high Eu doping concentrations, all Y2O3:Eu generated in H2/O2 flames had
the monoclinic structure. On the other hand, all particles generated in the H2/air flames
had the cubic structure. For the Y2O3:Eu particles generated in H2/O2 flames, XPS
results showed that the surface Eu concentration was several times higher than the
doping concentration. For Y2O3:Eu particles generated in H2/air flames, the surface Eu
concentration was equal to the doping concentration. For both types of particles, the
photoluminescence intensity reached a maximum corresponding to a surface Eu
concentration 40~50%. The photoluminescence intensity then decreased rapidly with
higher Eu doping concentration.
The effect of particle size and Eu doping concentration on crystal structure may
be explained by the interplay between surface energy and polymorphism. A mechanism
for this surface enrichment phenomenon was proposed based on the binary Eu2O3-Y2O3
phase diagram.
| Identifer | oai:union.ndltd.org:tamu.edu/oai:repository.tamu.edu:1969.1/ETD-TAMU-2009-05-574 |
| Date | 2009 May 1900 |
| Creators | Yim, Hoon |
| Contributors | Guo, Bing |
| Source Sets | Texas A and M University |
| Language | English |
| Detected Language | English |
| Type | Book, Thesis, Electronic Thesis, text |
| Format | application/pdf |
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