The three-dimensional x-ray structure of 2,2'-bipyridylglycinatochloro copper(II) dihydrate has been fully refined to a final R factor of 0.081. The bipyridyl and glycine ligands are arranged about the central copper atom in a square planar configuration while the chlorine atom is 2.635 angstroms above this plane directly over the copper atom. This unusually long distance is explained by the positioning of a glycine group on the opposite side of the square plane, resulting in a distorted octahedral arrangement. Also, the chlorine atom is linked to three oxygen atoms via hydrogen bonding, thus stabilizing the distorted octahedral complex.
| Identifer | oai:union.ndltd.org:unt.edu/info:ark/67531/metadc663591 |
| Date | 05 1900 |
| Creators | Neitzel, Conrad J. |
| Contributors | Desiderato, Robert, Brady, William Thomas |
| Publisher | North Texas State University |
| Source Sets | University of North Texas |
| Language | English |
| Detected Language | English |
| Type | Thesis or Dissertation |
| Format | vi, 54 leaves: ill., Text |
| Rights | Public, Neitzel, Conrad J., Copyright, Copyright is held by the author, unless otherwise noted. All rights |
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