¤@.Pyrolysis of 2-thiomethoxystyrylarenes 15a-c gave 2-(aryl-2-yl)benzo[b]arenes 22a-c and their isomers 23a-c and polycyclic aromatic hydrocarbons (PAH) 24a-c, respectively. Furthermore, pyrolysis of 15c also gave compounds 42¡B43¡B44 by breaking C-N single bond of 15c at higher temperature. In addition, photolysis of 15a-c gave photocyclic products 24a-c and 32a-c, respectively.
¤G.Pyrolysis of 2-(3-phenylpropenyl)anisole(18) and 2-(1-phenyl)anisole (19) gave 2-phenylbenzo[b]furan (13)¡Bbenzofuran (27)¡Bethylbenzene (28) and dibenzyl (29) as the main products.
¤T.Attempts to prepare hexaazatriphenylene derivatives 3 were carried by condensation between diamino dihydropyrazine compound 2 and hexaketocyclohexane (1).
| Identifer | oai:union.ndltd.org:NSYSU/oai:NSYSU:etd-0630108-172651 |
| Date | 30 June 2008 |
| Creators | Hsu, Chen-Ping |
| Contributors | Nein-Chen Chang, Teng-Yuan Dong, Yen-Ho Chu, Chin-Hsing Chou |
| Publisher | NSYSU |
| Source Sets | NSYSU Electronic Thesis and Dissertation Archive |
| Language | Cholon |
| Detected Language | English |
| Type | text |
| Format | application/pdf |
| Source | http://etd.lib.nsysu.edu.tw/ETD-db/ETD-search/view_etd?URN=etd-0630108-172651 |
| Rights | not_available, Copyright information available at source archive |
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