Excess nutrients, particularly phosphorus (P), significantly contribute to anthropogenic eutrophication, which negatively impacts ecosystems, human health, and the economy. Traditional Best Management Practices (BMPs) such as wet retention ponds prevent eutrophication by acting as a sink for nutrients, but can become a source of pollutants if not properly monitored and maintained. A proposed solution is a standalone, multi-stage filter system that can attach to BMPs with standing water for targeted removal of excess nutrients and with the potential to recycle the filter media. The studies in this dissertation seek to address the feasibility of this solution through the following tasks: 1.) develop a tool that can identify ponds and locations within ponds with high total phosphorus (TP) concentrations, 2.) evaluate filter media that can remove P and can be recycled along with captured P, and 3.) develop a filter system that can remove pollutants in separate stages for the option to recycle certain pollutants. The studies focused primarily on P because the nutrient has the potential to be recycled if captured within the filter. Models developed in the first task showed that TP concentrations in the water were correlated with the pond outlet, pH of the water, and iron concentrations. TP concentrations in the sediment were correlated with the pond's length-to-width ratio and the concentration of aluminum and copper. For the second task, a batch experiment and measurements of physicochemical properties were conducted on four biochars (corn stover pyrolized at 400°C , corn stover pyrolized at 600°C, mixed hardwood, and rice husk). Results indicated that mixed hardwood biochar could sorb dissolved phosphorus (DP) above a solution concentration of 2.9 mg P/L. The properties that could allow this biochar to sorb DP were a smaller negative surface charge, high surface area, smaller concentration of elemental P, and more water-extractable cations. A laboratory-scale test of a three-stage filter system was performed as part of the third task. The filter effectively separated nitrogen and P in different stages, but did not separate lead from P. Median water quality parameters (pH, conductivity, temperature, turbidity, dissolved oxygen, carbon, iron) met U.S. EPA recommended limits, but some parameters violated the recommended limits at a few time points. These studies demonstrate that excessive pollutant concentrations exist in current BMPs, which can benefit from a filter system. The filter system has the potential to collect pollutants separately provided that the correct media mix and configuration is identified such that P can be more completely isolated and water quality parameters are met. / PHD / Excess nutrients, particularly phosphorus (P), cause harmful algae blooms in the nation’s water bodies, which negatively impacts ecosystems, human health, and the economy. Structures such as wet retention ponds detain these nutrients by storing them, but can become a source of pollutants if not properly monitored and maintained. A proposed solution is a standalone, multi-stage filter system that can attach to wet retention ponds for targeted removal of excess nutrients and with the potential to recycle the filter media. The studies in this dissertation seek to address the feasibility of this solution through the following tasks: 1.) develop a tool that can identify ponds and locations within ponds with high total phosphorus (TP) concentrations, 2.) evaluate filter media that can remove dissolved P (DP) and can be recycled along with captured DP, and 3.) develop a filter system that can remove pollutants in separate stages for the option to recycle certain pollutants. The studies focused primarily on P because the nutrient has the potential to be recycled if captured within the filter. Models developed in the first task showed that TP concentrations in the water were correlated with the pond outlet, pH of the water, and iron concentrations. TP concentrations in the sediment were correlated with the pond’s length-to-width ratio and the concentration of aluminum and copper. For the second task, four biochars (corn stover pyrolized at 400°C, corn stover pyrolized at 600°C, mixed hardwood, and rice husk) were tested for their ability to collect DP. Only the mixed hardwood biochar was able to collect DP when the surrounding DP solution was higher than 2.9 mg P/L. A laboratory-scale test of a three-stage filter system was performed as part of the third task. The filter effectively separated nitrogen and P in different stages, but did not separate lead from P. Water quality parameters (pH, conductivity, temperature, turbidity, dissolved oxygen, carbon, iron) generally met U.S. EPA recommended limits, but some parameters violated the recommended limits at a few points in time. These studies demonstrate that excessive pollutant concentrations exist in current wet retention ponds, which can benefit from a filter system. The filter system has the potential to collect pollutants separately provided that the correct media mix and configuration is identified such that P can be more completely isolated and water quality parameters are met.
| Identifer | oai:union.ndltd.org:VTETD/oai:vtechworks.lib.vt.edu:10919/95908 |
| Date | 11 June 2018 |
| Creators | Houston, Stephanie Chung-Pei-Hua |
| Contributors | Biological Systems Engineering, Hession, W. Cully, Stephenson, Stephen Kurt, Eick, Matthew J., Easton, Zachary M. |
| Publisher | Virginia Tech |
| Source Sets | Virginia Tech Theses and Dissertation |
| Detected Language | English |
| Type | Dissertation |
| Format | ETD, application/pdf |
| Rights | In Copyright, http://rightsstatements.org/vocab/InC/1.0/ |
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