The complexes L(,2)Pt(SR)(,2), where L = PPh(,3), PMePh(,2), PMe(,2)Ph, were prepared in high purity and yield by treating the dichlorides with thiols and triethylamine under nitrogen atmosphere. Their geometry is cis for R = ('n)Pr, ('i)Pr, CH(,2)Ph and trans for R = 4-C(,6)H(,4)Me. Reactions of cis-L(,2)PtCl(,2) and H(,2)S/K(,2)CO(,3) or NaSH in the presence of dichloromethane afforded the complexes L(,2)Pt(S(,2)CH(,2)), containing the novel bidentate methanedithiolato ligand. The thiolato-bridged dimers {LPt(SR')(,2)}(,2), where R' = CH(,2)Ph, 4-C(,6)H(,4)Me, were isolated by fusion of the appropriate monomers in vacuo. The compound {(PMePh(,2))Pt(SCH(,2)Ph)((mu)-SCH(,2)Ph)}(,2) has the cis-symmetrical structure. Treatment of the complexes cis-L(,2)Pt(SCH(,2)Ph)(,2) with phtNSSNpht, where H-Npht = phthalimide, led to stepwise displacement of the phenylmethanethiolato ligands by phthalimido groups. / The first platinadisulfanes, complexes of the type cis-(PPh(,3))(,2)Pt(Npht)(SSR''), where R'' = ('n)Pr, ('i)Pr, CH(,2)Ph, 4-C(,6)H(,4)Me and Npht, were synthesized in good yield by the oxidative addition of R''SSNpht to (PPh(,3))(,2)Pt(C(,2)H(,4)). Similarly, addition of R''SNpht gave cis-(PPh(,3))(,2)Pt(Npht)(SR'').
| Identifer | oai:union.ndltd.org:LACETR/oai:collectionscanada.gc.ca:QMM.77147 |
| Date | January 1981 |
| Creators | Lai, Rabin Diwan. |
| Publisher | McGill University |
| Source Sets | Library and Archives Canada ETDs Repository / Centre d'archives des thèses électroniques de Bibliothèque et Archives Canada |
| Language | English |
| Detected Language | English |
| Type | Electronic Thesis or Dissertation |
| Format | application/pdf |
| Coverage | Doctor of Philosophy (Department of Chemistry) |
| Rights | All items in eScholarship@McGill are protected by copyright with all rights reserved unless otherwise indicated. |
| Relation | alephsysno: 000139379, proquestno: AAINK58091, Theses scanned by UMI/ProQuest. |
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