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Conversion of BaF₂ to BaO for in-situ growth of Y-Ba-Cu-O thin films

The Y₁Ba₂Cu₃0x superconducting thin films were made by both sequential electron-beam evaporation and co-evaporation of Cu, BaF₂ and Y, followed with high temperature post-deposition annealing.
The possibility of making Y₁Ba₂Cu₃0x superconducting film in situ with BaF₂ as the Ba source was investigated by studying the conditions of in situ conversion of BaF₂ to BaO. The BaO concentration in the film as function of the substrate temperature was estimated with an equilibrium thermodynamic model and found to agree with the experimental results.
A brief experimental and theoretical exploration of BaCl₂ also showed that BaCl₂ does not have any advantage over BaF2 as the Ba source for in situ growth of Y-Ba-Cu-0 films from the growth temperature point of view. / Science, Faculty of / Physics and Astronomy, Department of / Graduate

Identiferoai:union.ndltd.org:UBC/oai:circle.library.ubc.ca:2429/28987
Date January 1990
CreatorsGao, Yuan
PublisherUniversity of British Columbia
Source SetsUniversity of British Columbia
LanguageEnglish
Detected LanguageEnglish
TypeText, Thesis/Dissertation
RightsFor non-commercial purposes only, such as research, private study and education. Additional conditions apply, see Terms of Use https://open.library.ubc.ca/terms_of_use.

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