In this study, we focus on the substituent effect of the diketone ligands on the structural variation of £]- diketonato metal complexes containing N,N-dimethyl formamide (DMF). Three £]-diketones (hfac, bztf, bzbz) were used, and six-, five-, four- coordinated complexes were found accordingly. It is surprising to find that all six metal-oxygen bonds in the M(hfac)2(DMF)2 complexes are of equal length, seemly in violation of Jahn-Teller theorem. Possible reasons for this observation were discussed in this thesis.
| Identifer | oai:union.ndltd.org:NSYSU/oai:NSYSU:etd-0827101-155903 |
| Date | 27 August 2001 |
| Creators | Yung, Tun-Yuang |
| Contributors | none, none, Michael Yen-nan Chiang |
| Publisher | NSYSU |
| Source Sets | NSYSU Electronic Thesis and Dissertation Archive |
| Language | Cholon |
| Detected Language | English |
| Type | text |
| Format | application/pdf |
| Source | http://etd.lib.nsysu.edu.tw/ETD-db/ETD-search/view_etd?URN=etd-0827101-155903 |
| Rights | withheld, Copyright information available at source archive |
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