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THE DETECTION OF SHORT-LIVED REACTION INTERMEDIATES IN SOLUTION, CHARACTERIZATION OF METAL COMPLEXES, AND THE CONFORMATIONAL CHANGE OF 1-BROMOPROPANE UPON BINDING TO ΑLPHA-CYCLODEXTRIN

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<p>The development of a novel technique employing the use of a linear quadrupole ion trap mass spectrometer coupled to a Nd:YAG laser and a home-built fast reagent-mixing apparatus is detailed and used to detect the short-lived tetrahedral reaction intermediate of the reaction of acetyl chloride with ethanol in microdroplets. Additionally, tandem and high-resolution mass spectrometry is used to characterize potential precursors for solution-processed metal selenide semiconductors in order to determine a synthetic route to sulfur-free thin films. Lastly, Raman MCR (multivariate curve resolution) spectroscopy is used to study the binding-induced conformational change of 1-bromopropane upon binding to α-cyclodextrin as a model system to examine guest conformational changes upon binding to a host molecule.</p>

  1. 10.25394/pgs.21685142.v1
Identiferoai:union.ndltd.org:purdue.edu/oai:figshare.com:article/21685142
Date07 December 2022
CreatorsVictoria Boulos (14228024)
Source SetsPurdue University
Detected LanguageEnglish
TypeText, Thesis
RightsCC BY 4.0
Relationhttps://figshare.com/articles/thesis/THE_DETECTION_OF_SHORT-LIVED_REACTION_INTERMEDIATES_IN_SOLUTION_CHARACTERIZATION_OF_METAL_COMPLEXES_AND_THE_CONFORMATIONAL_CHANGE_OF_1-BROMOPROPANE_UPON_BINDING_TO_LPHA-CYCLODEXTRIN/21685142

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