The surface modification of UHMPE fibers by atmospheric pressure plasma treatments was examined. In one study the aging effects of atmospheric plasma treatments were studied. UHMPE fibers were treated for 0.5 and 1 min with He/O2/air gas and for 2 and 4 min with He/air gas by atmospheric pressure plasma on a capacitively coupled device. The samples were tested for fiber/epoxy interfacial shear strength using the microbond technique at time intervals of 0, 3, 15 and 30 days after initial plasma treatment. Interfacial shear strengths (IFSS) for plasma treated fibers were 2 - 3 times as high as that of the control. The IFSS for the plasma treated fibers remained constant up to 15 days and then decreased afterwards. XPS Analysis and SEM photographs characterized the fiber surface modification. In a second study, delamination phenomena was studied by the transverse compression of seven-fiber bundle UHMPE microcomposites, a peeling test of laminated plain weave UHMPE fabric and tensile shear strength testing of a ten-layer plain weave UHMPE / Epoxy flat panel composite. Results showed a 49% increase in yield modulus of the plasma treated sample compared to the control in the transverse compression test. There was an 82.5% increase in bonding strength for the plasma treated sample during the peel test and a 25.7% increase in interlaminar shear strength of the ten-ply UHMPE composite proving that atmospheric plasma treatments are very effective in surface modification on a microscopic fiber level and a full-scale composite production level.
| Identifer | oai:union.ndltd.org:NCSU/oai:NCSU:etd-11012002-080351 |
| Date | 14 November 2002 |
| Creators | Jensen, Christina Louise |
| Contributors | Dr. Marian McCord, Dr. Mohamed Bourham, Dr. Yiping Qiu |
| Publisher | NCSU |
| Source Sets | North Carolina State University |
| Language | English |
| Detected Language | English |
| Type | text |
| Format | application/pdf |
| Source | http://www.lib.ncsu.edu/theses/available/etd-11012002-080351/ |
| Rights | unrestricted, I hereby certify that, if appropriate, I have obtained and attached hereto a written permission statement from the owner(s) of each third party copyrighted matter to be included in my thesis, dissertation, or project report, allowing distribution as specified below. I certify that the version I submitted is the same as that approved by my advisory committee. I hereby grant to NC State University or its agents the non-exclusive license to archive and make accessible, under the conditions specified below, my thesis, dissertation, or project report in whole or in part in all forms of media, now or hereafter known. I retain all other ownership rights to the copyright of the thesis, dissertation or project report. I also retain the right to use in future works (such as articles or books) all or part of this thesis, dissertation, or project report. |
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