Lam, Pui Chi. / Thesis submitted in: November 2006. / Thesis (M.Phil.)--Chinese University of Hong Kong, 2007. / Includes bibliographical references. / Abstracts in English and Chinese. / Table of Contents --- p.i / Acknowledgements --- p.v / Abstract --- p.vi / 摘要 --- p.viii / List of Compounds --- p.x / Abbreviations --- p.xiii / Chapter CHAPTER 1. --- A GENERAL INTRODUCTION TO METAL AMIDES / Chapter 1.1 --- GENERAL BACKGROUND --- p.1 / Chapter 1.2 --- OBJECTIVES OF THIS WORK --- p.7 / Chapter 1.3 --- REFERENCES FOR CHAPTER1 --- p.8 / Chapter CHAPTER 2. --- SYNTHESIS AND STRUCTURES OF GROUP 4 METAL AMIDES / Chapter 2.1 --- INTRODUCTION --- p.15 / Chapter 2.1.1 --- General Background --- p.15 / Chapter 2.1.2 --- Common Preparation Methods for Group 4 Metal Amides --- p.15 / Chapter 2.1.3 --- "An Overview on Titanium(IV), Zirconium(IV) and Hafnium(IV) Amides" --- p.17 / Chapter 2.2 --- AIMS OF OUR STUDIES --- p.26 / Chapter 2.3 --- RESULTS AND DISCUSSION --- p.27 / Chapter 2.3.1 --- Synthesis of the Ligand Precursor (HL1) and the Corresponding Lithium Derivative [Li(L1tmeda)] --- p.27 / Chapter 2.3.2 --- Synthesis and Structures of Monomeric and Dimeric Titanium(IV) Amides --- p.28 / Chapter 2.3.2.1 --- Synthesis of [Ti(L1 )Cl2(μ-Cl)2] (V and [TiL1)Ch3(THF)] (4) --- p.28 / Chapter 2.3.2.2 --- Reactivity Studies --- p.31 / Chapter 2.3.2.3 --- Physical Characterization of Compounds 3 and 4 --- p.33 / Chapter 2.3.2.4 --- Molecular Structures of Compounds 3 and 4 --- p.36 / Chapter 2.3.3 --- Synthesis and Structures of Mononuclear Zirconium(IV) and Hafnium(IV) Amides --- p.44 / Chapter 2.3.3.1 --- Synthesis of[M(L1)3Cl] (M = Zr 5 and Hf6) --- p.44 / Chapter 2.3.3.2 --- Reactivity Studies --- p.45 / Chapter 2.3.3.3 --- Synthesis of[MCL1)3H] (M = Zr7 and Hf8) --- p.48 / Chapter 2.3.3.4 --- Reactivity Studies of Compound7 --- p.49 / Chapter 2.3.3.5 --- Physical Characterization of Compound 8 --- p.51 / Chapter 2.3.3.6 --- Molecular Structures of Compound 8 --- p.53 / Chapter 2.3.3.7 --- Synthesis of [Zr(L1)3Me] (9) --- p.57 / Chapter 2.3.3.8 --- Reactivity Studies of Compound 9 --- p.58 / Chapter 2.3.3.9 --- Physical Characterization of Compound 9 --- p.59 / Chapter 2.3.3.10 --- Molecular Structure of Compound 9 --- p.60 / Chapter 2.4 --- EXPERIMENTALS FOR CHAPTER 2 --- p.64 / Chapter 2.4.1 --- General Procedures --- p.64 / Chapter 2.4.2 --- Synthesis of Compounds --- p.65 / REFERENCES FOR CHAPTER 2 --- p.68 / Chapter CHAPTER 3. --- SYNTHESIS AND STRUCTURES OF VANADIUM(III) AMIDO AND BENZAMIDINATO COMPLEXES / Chapter 3.1 --- INTRODUCTION --- p.74 / Chapter 3.1.1 --- General Background --- p.74 / Chapter 3.1.2 --- A Brief Introduction on Metal Amidinates --- p.75 / Chapter 3.1.3 --- An Overview on Vanadium(III) Amides --- p.77 / Chapter 3.1.4 --- An Overview on Vanadium(III) Amidinates --- p.82 / Chapter 3.2 --- AIMS OF OUR STUDIES --- p.85 / Chapter 3.3 --- RESULTS AND DISCUSSION --- p.86 / Chapter 3.3.1 --- Synthesis and Structures of Dinuclear Vanadium(III) Amides --- p.86 / Chapter 3.3.1.1 --- Synthesis of[V(L1)2(μ~Cl)]2(10) --- p.86 / Chapter 3.3.1.2 --- Reactivity Studies --- p.88 / Chapter 3.3.1.3 --- Synthesis of [V(L1)2(μ-H)]2 (11) --- p.90 / Chapter 3.3.1.4 --- Physical Characterization of Compounds 10 and 11 --- p.90 / Chapter 3.3.1.5 --- Molecular Structures of Compounds 10 and 11 --- p.94 / Chapter 3.3.2 --- Synthesis and Structure of Mononuclear Vanadium(III) Benzamidinate --- p.102 / Chapter 3.3.2.1 --- "Synthesis of [Li(L2)(tmeda)] (13) (L2 = [PhC(NSiMe3) (NC6H3Me2-2, 6)])" --- p.102 / Chapter 3.3.2.2 --- Synthesis of [V(L2)2Cl] (14) and trans´ؤ[V(tmeda)2Cl2] (15) --- p.103 / Chapter 3.3.2.3 --- Reactivity Studies --- p.104 / Chapter 3.3.2.4 --- Physical Characterization of Compound 14 --- p.107 / Chapter 3.3.2.5 --- Molecular Structure of Compound 14 --- p.107 / Chapter 3.4 --- EXPERIMENTALS FOR CHAPTER 3 --- p.111 / Chapter 3.4.1 --- General Procedures --- p.111 / Chapter 3.4.2 --- Synthesis of Compounds --- p.112 / Chapter 3.5 --- REFERENCES FOR CHAPTER 3 --- p.115 / Chapter CHAPTER 4. --- SYNTHESIS AND STRUCTURES OF CHROMIUM AMIDO AND BENZAMIDINATO COMPLEXES / Chapter 4.1 --- INTRODUCTION --- p.122 / Chapter 4.1.1 --- General Background --- p.122 / Chapter 4.1.2 --- An Overview on Chromium(III) Amides --- p.122 / Chapter 4.1.3 --- An Overview on Chromium(II) Amidinates --- p.125 / Chapter 4.2 --- AIMS OF OUR STUDIES --- p.129 / Chapter 4.3 --- RESULTS AND DISCUSSION --- p.130 / Chapter 4.3.1 --- Synthesis and Structures of A Monomeric Chromium(III) Amide and A Chromium(II) Benzamidinate --- p.130 / Chapter 4.3.1.1 --- Synthesis of[Cr(L1)3] (16) --- p.130 / Chapter 4.3.1.2 --- Synthesis of [Cr(L2)2] (17) --- p.132 / Chapter 4.3.1.3 --- Physical Characterization of Compounds 16 and 17 --- p.133 / Chapter 4.3.1.4 --- Molecular Structures of Compounds 16 and 17 --- p.135 / Chapter 4.4 --- EXPERIMENT ALS FOR CHAPTER 4 --- p.141 / Chapter 4.4.1 --- General Procedures --- p.141 / Chapter 4.4.2 --- Synthesis of Compounds --- p.141 / Chapter 4.5 --- REFERENCES FOR CHAPTER 34 --- p.144 / APPENDIX 1 / Physical Measurements and X-Ray Crystallography --- p.147 / APPENDIX 2 / "Mass Spectra, 1'H and 13C{]H} NMR Spectra, and IR Spectra" --- p.148 / APPENDIX 3 --- p.172 / Table A-1. Selected crystallographic data for compounds 3-4 --- p.173 / Table A-2. Selected crystallographic data for compounds 8-9 --- p.174 / Table A-3. Selected crystallographic data for compounds 10-11 --- p.175 / Table A-4. Selected crystallographic data for compounds 14，16-17 --- p.176
| Identifer | oai:union.ndltd.org:cuhk.edu.hk/oai:cuhk-dr:cuhk_325864 |
| Date | January 2007 |
| Contributors | Lam, Pui Chi., Chinese University of Hong Kong Graduate School. Division of Chemistry. |
| Source Sets | The Chinese University of Hong Kong |
| Language | English, Chinese |
| Detected Language | English |
| Type | Text, bibliography |
| Format | print, xiii, 176 leaves : ill. ; 30 cm. |
| Rights | Use of this resource is governed by the terms and conditions of the Creative Commons “Attribution-NonCommercial-NoDerivatives 4.0 International” License (http://creativecommons.org/licenses/by-nc-nd/4.0/) |
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