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Synthesis, structures and reactivities of low-valent late transition metal amides.

Chung Hei Lam. / Thesis (M.Phil.)--Chinese University of Hong Kong, 2001. / Includes bibliographical references. / Abstracts in English and Chinese. / Table of Contents --- p.i / Acknowledgements --- p.iv / Abstracts --- p.v / 摘要 --- p.vii / List of Compounds --- p.ix / List of Tables --- p.xii / List of Figures --- p.xiv / Abbreviations --- p.xv / Chapter CHAPTER 1. --- SYNTHESIS OF LATE TRANSITION METAL AMIDES / Chapter 1.1 --- GENERAL BACKGROUND --- p.1 / Chapter 1.2 --- PREPARATIONS OF LATE TRANSITION METAL AMIDES --- p.2 / Chapter 1.3 --- OBJECTIVES OF THIS WORK --- p.3 / Chapter 1.4 --- REFERENCES FOR CHAPTER1 --- p.5 / Chapter CHAPTER 2. --- "SYNTHESIS, STRUCTURES AND REACTIVITIES OF IRON(II) AND COBALT(II) AMIDES" / Chapter 2.1 --- INTRODUCTION --- p.7 / Chapter 2.1.1 --- A General Review on Iron(II) and Cobalt (II) Amides --- p.7 / Chapter 2.1.2 --- A General Review on Iron(II) and Cobalt(II) Thiolates --- p.9 / Chapter 2.1.3 --- A General Review on Iron(II) and Cobalt(II) Alkoxides and Aryloxides --- p.11 / Chapter 2.2 --- RESULTS AND DISCUSSION --- p.13 / Chapter 2.2.1 --- Synthesis of the Ligand Precursor LH (1) and the Corresponding Lithium Reagents [Li(L)(TMEDA)] (2) and LiL (3) --- p.13 / Chapter 2.2.2 --- Synthesis´ة Structures and Reactivities of Mononuclear Iron(II) and Cobalt(II) Amides --- p.14 / Chapter 2.2.2.1 --- Synthesis of Mononuclear Iron(II) and Cobalt(II) Amides --- p.14 / Chapter 2.2.2.2 --- Reactions of Compound 4 with ArMe OH and ArSH --- p.18 / Chapter 2.2.2.3 --- Physical Characterization of Compounds 4-6 --- p.19 / Chapter 2.2.2.4 --- Molecular Structures of Compounds 4-6 --- p.20 / Chapter 2.2.3 --- "Synthesis, Structures and Reactivities of Binuclear Iron(II) and Cobalt (II) Amides" --- p.31 / Chapter 2.2.3.1 --- Synthesis of Binuclear Iron(II) and Cobalt(II) Amides --- p.31 / Chapter 2.2.3.2 --- Reactions of Compounds 7 and 8 with Protic Reagents --- p.33 / Chapter 2.2.3.3 --- "Attempted Reactions of Compounds 7 and 8 with 3,5-di-tert- butylcatechol" --- p.35 / Chapter 2.2.3.4 --- Physical Characterization of Compounds 7-14 --- p.35 / Chapter 2.2.3.5 --- Molecular Structures of Compounds 7-10 and 13-14 --- p.38 / Chapter 2.3 --- EXPERIMENTALS FOR CHAPTER 2 --- p.57 / Chapter 2.4 --- REFERENCES FOR CHAPTER 2 --- p.64 / Chapter CHAPTER 3. --- SYNTHESIS AND STRUCTURES OF MANGANESE(II) AMIDES / Chapter 3.1 --- INTRODUCTION --- p.68 / Chapter 3.2 --- RESULTS AND DISCUSSION --- p.70 / Chapter 3.2.1 --- Synthesis of Manganese(II) Amide --- p.70 / Chapter 3.2.2 --- Physical Characterization of Compound 15 --- p.72 / Chapter 3.2.3 --- Molecular Structure of Compound 15 --- p.73 / Chapter 3.3 --- EXPERIMENTALS FOR CHAPTER 3 --- p.78 / Chapter 3.4 --- REFERENCES FOR CHAPTER 3 --- p.79 / "APPENDIX 1 General Procedures, Physical Measurements and X-ray Structure Analysis" --- p.81 / APPENDIX 2 Table A-1. Selected crystallographic data for compounds 4-6. --- p.84 / Table A-2. Selected crystallographic data for compounds 7-10. --- p.85 / Table A-3. Selected crystallographic data for compounds 13-15 --- p.86

Identiferoai:union.ndltd.org:cuhk.edu.hk/oai:cuhk-dr:cuhk_323410
Date January 2001
ContributorsLam, Chung Hei., Chinese University of Hong Kong Graduate School. Division of Chemistry.
Source SetsThe Chinese University of Hong Kong
LanguageEnglish, Chinese
Detected LanguageEnglish
TypeText, bibliography
Formatprint, xvi, 86 leaves : ill. ; 30 cm.
RightsUse of this resource is governed by the terms and conditions of the Creative Commons “Attribution-NonCommercial-NoDerivatives 4.0 International” License (http://creativecommons.org/licenses/by-nc-nd/4.0/)

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