by Au Yeung Ho Yu. / Thesis (M.Phil.)--Chinese University of Hong Kong, 2006. / Includes bibliographical references. / Abstracts in English and Chinese. / Abstract --- p.i / 摘要 --- p.iii / Acknowledgement --- p.v / Table of Contents --- p.vi / Abbreviations --- p.ix / List of Compounds --- p.x / Chapter Chapter 1 --- A General Introduction To Late Transition Metal Amides / Chapter 1.1 --- General Background --- p.1 / Chapter 1.2 --- An Overview of Late Transition Metal Amides --- p.2 / Chapter 1.3 --- Objectives of This Work --- p.7 / Chapter 1.4 --- References for Chapter1 --- p.9 / Chapter Chapter 2 --- Late Transition Metal Complexes Derived From 2-Pyridyl Amido Ligand / Chapter 2.1 --- General Background / Chapter 2.1.1 --- A Brief Introduction to Pyridine-Functionalized Amido Ligands --- p.13 / Chapter 2.1.2 --- Late Transition Metal Complexes Supported by 2-Pyridyl Amido Ligands --- p.14 / Chapter 2.2 --- Aims of Our Study --- p.18 / Chapter 2.3 --- Result and Discussion / Chapter 2.3.1 --- Preparation of the [N(CH2But)(2-C5H3N-6-Me)]- Ligand and the Corresponding Lithium Derivatives --- p.19 / Chapter 2.3.2 --- Syntheses and Structures of Iron(II) and Cobalt(II) Amides / Chapter 2.3.2.1 --- "Synthesis of [M(L1)2(HL1)] [M = Fe (6), Co (7)]" --- p.20 / Chapter 2.3.2.2 --- Physical Characterization of Compounds 6 and7 --- p.24 / Chapter 2.3.2.3 --- Molecular Structures of Compounds 6 and7 --- p.24 / Chapter 2.4 --- Experimentals for Chapter 2 --- p.31 / Chapter 2.5 --- References for Chapter 2 --- p.34 / Chapter Chapter 3 --- Synthetic and Structural Studies of Late Transition Metal Anilides / Chapter 3.1 --- An Overview on Anilido Complexes --- p.40 / Chapter 3.2 --- Aims of Our Study --- p.45 / Chapter 3.3 --- Result and Discussion / Chapter 3.3.1 --- Aniline Precursors and The Lithium Derivatives / Chapter 3.3.1.1 --- Syntheses of the Aniline Precusors HLn (n = 2-5) --- p.46 / Chapter 3.3.1.2 --- Syntheses of Lithium Derivatives of Ln (n = 2-5) --- p.47 / Chapter 3.3.1.3 --- Physical Characterization of Compounds 11-13 --- p.48 / Chapter 3.3.1.4 --- "Molecular Structures of Compounds 11a, 12a and 12b" --- p.49 / Chapter 3.3.2 --- Syntheses and Structures of Late Transition Metal Anilides / Chapter 3.3.2.1 --- Syntheses of N-Silylated Anilides --- p.57 / Chapter 3.3.2.2 --- Physical Characterization of Compounds 14-20 --- p.64 / Chapter 3.3.2.3 --- Molecular Structures of Compounds 14-20 --- p.65 / Chapter 3.3.2.4 --- Syntheses of N-Alkylated Anilides --- p.89 / Chapter 3.3.2.5 --- Physical Characterization of Compounds 21-26 --- p.92 / Chapter 3.3.2.6 --- "Molecular Structures of Compounds 21, 23, 25 and 26" --- p.93 / Chapter 3.4 --- Experimentals for Chapter 3 --- p.103 / Chapter 3.5 --- References for Chapter 3 --- p.112 / Chapter Chapter 4 --- Reactions of Late Transition Metal Anilides and Their Derivatives / Chapter 4.1 --- General Background / Chapter 4.1.1 --- Reactions of Late Transition Metal Amides --- p.124 / Chapter 4.1.2 --- A Brief Introduction to Oxidative Coupling of Phenols --- p.129 / Chapter 4.1.3 --- A Brief Overview on the Ring-Opening Polymerization of Cyclic Esters --- p.130 / Chapter 4.2 --- Aims of Our Study --- p.132 / Chapter 4.3 --- Results and Discussion / Chapter 4.3.1 --- Reactions of Late Transition Metal Anilides and Their Derivatives / Chapter 4.3.1.1 --- Ligand Substitution --- p.133 / Chapter 4.3.1.2 --- Chloride Abstraction --- p.137 / Chapter 4.3.1.3 --- Chemical Reduction --- p.138 / Chapter 4.3.1.4 --- Reaction with Unsaturated Compounds --- p.139 / Chapter 4.3.1.5 --- Physical Characterization of Compounds 27-33 --- p.140 / Chapter 4.3.1.6 --- Molecular Structures of Compounds 27-33 --- p.142 / Chapter 4.3.2 --- Oxidation of Bisaryloxide Complexes --- p.162 / Chapter 4.3.3 --- The Ring-Opening Polymerization of e-Caprolactone --- p.167 / Chapter 4.4 --- Experimentals for Chapter 4 --- p.171 / Chapter 4.5 --- References for Chapter 4 --- p.176 / "Appendix 1 General Procedures, Physical Measurements and X-Ray Structure Analysis" --- p.187 / Appendix 2 NMR Spectra of Compounds --- p.189 / Appendix 3 Selected Crystallographic Data --- p.202
| Identifer | oai:union.ndltd.org:cuhk.edu.hk/oai:cuhk-dr:cuhk_325670 |
| Date | January 2006 |
| Contributors | Au Yeung, Ho Yu., Chinese University of Hong Kong Graduate School. Division of Chemistry. |
| Source Sets | The Chinese University of Hong Kong |
| Language | English, Chinese |
| Detected Language | English |
| Type | Text, bibliography |
| Format | print, xvi, 212 leaves : ill. ; 30 cm. |
| Rights | Use of this resource is governed by the terms and conditions of the Creative Commons “Attribution-NonCommercial-NoDerivatives 4.0 International” License (http://creativecommons.org/licenses/by-nc-nd/4.0/) |
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