Chong Kim Hung. / Thesis (M.Phil.)--Chinese University of Hong Kong, 2005. / Includes bibliographical references. / Abstracts in English and Chinese. / Table of contents --- p.vi / Acknowledgements --- p.i / Abstract --- p.ii / 摘要 --- p.iv / List of Compounds --- p.ix / Synthesized / Abbreviations --- p.x / Chapter Chapter 1 --- Reactivity of Pyridyl-1-azaallyl Enamido Germanium(II) Chloride / Chapter 1.1 --- Introduction --- p.1 / Chapter 1.1.1 --- General Aspects of Reactivity of Heteroleptic Germylenes --- p.1 / Chapter 1.1.2 --- Synthesis of Pyridyl-1 -azaallyl Germanium(II) Chloride Complex --- p.10 / Chapter 1.1.3 --- Objectives of This Work --- p.12 / Chapter 1.2 --- Results and Discussion --- p.14 / Chapter 1.2.1.1 --- Synthesis of Chalcogenonyl Halide Complexes --- p.15 / Chapter 1.2.1.2 --- Spectroscopic Properties of 33 and 34 --- p.15 / Chapter 1.2.1.3 --- "Molecular Structures of [Ge(E){N(SiMe3)C(Ph)- C(SiMe3)(C5H4N-2)}Cl] (E = S (33), Se (34))" --- p.16 / Chapter 1.2.2.1 --- Synthesis of Group 11 Transition Metal-Pyridyl-1- Enamido Germanium(II) Chloride Complexes --- p.20 / Chapter 1.2.2.2 --- Spectroscopic Properties of 35 and 36 --- p.21 / Chapter 1.2.2.3 --- Molecular Structures of [Ge(CuI){N(SiMe3)- C(Ph)C(SiMe3)(C5H4N-2)}Cl(THF)2]4 (35) and [Ge(AuI){N(SiMe3)C(Ph)C(SiMe3)(C5H4N-2)}Cl] (36) --- p.22 / Chapter 1.2.3.1 --- "Reaction of Pyridyl-l-azaallyl Germanium(II) Chloride with 3,5-di-tert butyl-o-benzoqumone: Synthesis of [Ge{O(2,4-di-Bu'-C6H2)O}{N(SiMe3)C(Ph)C(SiMe3)- (C5H4N-2)}C1] (37)" --- p.27 / Chapter 1.2.3.2 --- Spectroscopic Properties of 37 --- p.27 / Chapter 1.2.3.3 --- "Molecular Structure of [Ge{0(2,4-di-Bu'- C6H2)O} {N(SiMe3)C(Ph)C(SiMe3)(C5H4N-2)}Cl] (37)" --- p.28 / Chapter 1.2.4.1 --- Synthesis of Boron-Germanium(II) Hydride Adduct --- p.31 / Chapter 1.2.4.2 --- Spectroscopic Properties of 38 --- p.31 / Chapter 1.2.4.3 --- Molecular Structure of [Ge(BH3){N(SiMe3)C(Ph)- C(SiMe3)(C5H4N-2)}H] (38) --- p.32 / Chapter 1.2.5.1 --- Substitution Reaction of Pyridyl-l-azaallyl Germanium(II) Chloride with Lithium Phenylacetylide --- p.34 / Chapter 1.2.5.2 --- Spectroscopic Properties of 39 --- p.34 / Chapter 1.2.5.3 --- Molecular Structure of [Ge{N(SiMe3)C(Ph)C(SiMe3)- (C5H4N-2)}(CCPh)] (39) --- p.35 / Chapter 1.2.6.1 --- Reaction of Pyridyl-l-azaallyl Germanium(II) Chloride with excess lithium; the formation of [GeC(Ph)C(SiMe3)(C5H4N-2)]2 (40) --- p.38 / Chapter 1.2.6.2 --- Spectroscopic Properties of 40 --- p.38 / Chapter 1.2.6.3 --- Molecular Structure of [GeC(Ph)C(SiMe3)(C5H4N-2)]2 (40) --- p.39 / Chapter 1.3 --- Experimental for Chapter 1 --- p.43 / Chapter 1.4 --- References for Chapter 1 --- p.50 / Chapter Chapter 2 --- Synthesis of Late Transition Metal Pyridyl-l-azaallyl Complexes / Chapter 2.1 --- Introduction --- p.55 / Chapter 2.1.1 --- General Aspects of 1 -azaallyl Metal Complexes --- p.55 / Chapter 2.1.2 --- Synthesis of Pyridyl-l-azaallyl Metal Complexes --- p.61 / Chapter 2.2 --- Results and Discussion --- p.68 / Chapter 2.2.1 --- Synthesis of Late Transition Metal Pyridyl-l-azaallyl Complexes --- p.68 / Chapter 2.2.2 --- Spectroscopic Properties of 55-59 --- p.70 / Chapter 2.2.3 --- Molecular Structures of Compounds 55-59 --- p.71 / Chapter 2.3 --- Experimental for Chapter 2 --- p.80 / Chapter 2.4 --- References for Chapter 2 --- p.83 / Appendix I / Chapter A. --- General Procedures --- p.86 / Chapter B. --- Physical and Analytical Measurements --- p.86 / Appendix II / Table A.1. Selected Crystallographic Data for Compounds 33-36 --- p.89 / Table A.2. Selected Crystallographic Data for Compounds 37-40 --- p.90 / Table A.3. Selected Crystallographic Data for Compounds 56-58 --- p.91 / Table A.4. Selected Crystallographic Data for Compound 59 --- p.92
| Identifer | oai:union.ndltd.org:cuhk.edu.hk/oai:cuhk-dr:cuhk_325287 |
| Date | January 2005 |
| Contributors | Chong, Kim Hung., Chinese University of Hong Kong Graduate School. Division of Chemistry. |
| Source Sets | The Chinese University of Hong Kong |
| Language | English, Chinese |
| Detected Language | English |
| Type | Text, bibliography |
| Format | print, xi, 92 leaves : ill. ; 30 cm. |
| Rights | Use of this resource is governed by the terms and conditions of the Creative Commons “Attribution-NonCommercial-NoDerivatives 4.0 International” License (http://creativecommons.org/licenses/by-nc-nd/4.0/) |
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