Suk-Yu Wong. / Thesis (M.Phil.)--Chinese University of Hong Kong, 2002. / Includes bibliographical references. / Abstracts in English and Chinese. / Acknowledgements --- p.i / Abstract --- p.ii / 中文摘要 --- p.iv / List of Compounds Synthesized --- p.vi / List of Abbreviation --- p.viii / Contents --- p.x / Chapter CHAPTER 1 --- Development of Phosphoranoimine as a Ligand for the Synthesis of Metal Complexes / Chapter 1.1 --- Introduction / Chapter 1.1.1 --- General Aspects of Phosphoranoimine --- p.1 / Chapter 1.1.2 --- General Aspects of Transition Metal Phosphoranoimine Complexes --- p.3 / Chapter 1.1.3 --- Reaction with Organolithium Compounds --- p.6 / Chapter 1.1.5 --- Objective of this Work --- p.8 / Chapter 1.2 --- Results and Discussion / Chapter 1.2.1 --- Synthesis and Characterization of Phosphoranoimine Ligand (9a and 9b) --- p.11 / Chapter 1.2.2 --- Synthesis of Dilithium Phosphoranoimine Complex (10a) --- p.14 / Chapter 1.2.3 --- Synthesis of Monolithium Phosphoranoimine Complex (10b) --- p.16 / Chapter 1.2.4 --- "Molecular Structures of Dilithium Complex and Monolithium Complex [Li2{2，6-(Me3SiN=PPh2CH)2C5H3N}THF] (10a) and [Li{2,6-(Me3SiN=PPri2CH)(Me3SiN=PPri2CH2)C5H3N}] (10b)" --- p.17 / Chapter 1.3 --- Experimental Section --- p.21 / Chapter 1.4 --- References --- p.27 / Chapter CHAPTER 2 --- Synthesis and Characterization of Transition Metal Complexes Containing Phosphoranoimine Ligands / Chapter 2.1 --- Introduction --- p.30 / Chapter 2.2 --- Results and Discussion / Chapter 2.2.1 --- "Synthesis and Characterization of Titanium(IV) Phosphoranoimido Complexes [Ti{N=(2-CH2Py)PPr i2 }C13(THF)] (11) and [Ti2{ {N=PPh2CH2}2 C5H3N-2,6}{(μ-Cl)2Cl4(THF)2}]n (12)" --- p.33 / Chapter 2.2.2 --- "Molecular Structures of [Ti{N=(2-CH2Py)PPri2}Cl3(THF)] (11) and [Ti2{{N=PPh2CH2}2C5H3N-2,6}{{471}-Cl)2Cl4(THF)2}]n (12)" --- p.36 / Chapter 2.2.3 --- "Synthesis and Characterization of Iron(II) Complexes [Fe{(2-CH2Py)PR2=NSiMe3}C12] (R = Ph, 13a; Pri, 13b)" --- p.42 / Chapter 2.2.4 --- "Molecular Structures of [Fe{(2-CH2Py)PR2=NSiMe3}Cl2] (R = Ph, 13a; Pri, 13b)" --- p.43 / Chapter 2.2.5 --- "Synthesis and Characterization of Cobalt(II) Complexes [Co{(2-CH2Py)PR2=NSiMe3}Cl2] (R = Ph, 14a; Pri，14b)" --- p.46 / Chapter 2.2.6 --- "Molecular Structures of [Co{(2-CH2Py)PR2=NSiMe3}Cl2] (R = Ph, 14a; Pri, 14b)" --- p.47 / Chapter 2.2.7 --- "Synthesis and Characterization of Copper(I) Complexes [Cu{(2-CH2Py)PPh2=NSiMe3 }I]2 (15a), [Cu{ (2-CH2Py)PPri2=NSiMe3 }I] (15b) and [Cu{2,6-(Me3SiN=PPri2CH2)2C5H3N}]+ [Cul2]-(16)" --- p.50 / Chapter 2.2.8 --- "Molecular Structures of [Cu{(2-CH2Py)PPh2=NSiMe3}I]2 (15a), [Cu{(2-CH2Py)PPri2=NSiMe3} I] (15b) and [Cu{2,6-(Me3SiN=PPri2CH2)2C5H3N}]+ [Cul2]- (16)" --- p.53 / Chapter 2.2.9 --- Spectroscopic properties of compounds 11-16 --- p.58 / Chapter 2.3 --- Experimental Section --- p.60 / Chapter 2.4 --- References --- p.64 / Chapter CHAPTER 3 --- Synthesis and Characterization of Group 8 Transition Metal Complexes Containing Phosphoranoimine Ligands / Chapter 3.1 --- Introduction --- p.65 / Chapter 3.2 --- Results and Discussion / Chapter 3.2.1 --- "Synthesis and Characterization of Nickel(II) Complexes [Ni{(2-CH2Py)PR2=NSiMe3 }Br2] (R = Ph, 17a; Pri, 17b)" --- p.68 / Chapter 3.2.2 --- "Molecular Structures of [Ni{(2-CH2Py)PR2=NSiMe3}Br2] (R = Ph, 17a; Pri, 17b)" --- p.69 / Chapter 3.2.3 --- "Synthesis and Characterization of hydrolyzed Nickel(II) and Palladium(II) Complexes [Ni{2,6-(HN=PPh2CH2)(Me3SiN=PPh2CH2) C5H3N}Br]+[Br]- (18), [(EtOH)Ni{2，6-(HN=PPh2CH2)2- C5H3N}C1]+[C1]- (19) and [Pd{(2-CH2Py)PPh2=NH}Cl2] (20)" --- p.72 / Chapter 3.2.4 --- "Molecular Structures of [Ni{2,6-(HN=PPh2CH2)(Me3SiN=PPh2CH2) C5H3N }Br]+[Br]- (18) and [(EtOH)Ni{2,6-(HN=PPh2CH2)2- C5H3N}C1]+[C1]- (19)，and [Pd{ (2-CH2Py)PPh2=NH}Cl2] (20 )" --- p.75 / Chapter 3.2.5 --- "Synthesis and Characterization of Ionic Palladium(II) Complex [Pd{2,6-(Me3SiN = PPh2CH2)2C5H3N}Cl]+[Cl]- (21)" --- p.80 / Chapter 3.2.6 --- "Molecular Structure of[Pd{2,6-(Me3SiN=PPh2CH2)2C5H3N}Cir[Cir]- (21)" --- p.81 / Chapter 3.2.7 --- Spectroscopic properties of compounds 17-21 --- p.83 / Chapter 3.3 --- Experimental Section --- p.84 / Chapter 3.4 --- References --- p.87 / Chapter CHAPTER 4 --- Reactivity of Phosphoranoimine Complexes on Ethylene Polymerization / Chapter 4.1 --- Introduction / Chapter 4.1.1 --- A Brief Review on Olefin Polymerization --- p.89 / Chapter 4.2 --- Results and Discussion --- p.92 / Chapter 4.3 --- Experimental Section --- p.94 / Chapter 4.4 --- References --- p.95 / APPENDIX I / Crystallographic Data and Refinement Parameters --- p.96 / APPENDIX II / Chapter A. --- General Experimental Procedures and Physical Measurement --- p.105 / Chapter B. --- X-ray Crystallography --- p.105
| Identifer | oai:union.ndltd.org:cuhk.edu.hk/oai:cuhk-dr:cuhk_323845 |
| Date | January 2002 |
| Contributors | Wong, Suk-Yu., Chinese University of Hong Kong Graduate School. Division of Chemistry. |
| Source Sets | The Chinese University of Hong Kong |
| Language | English, Chinese |
| Detected Language | English |
| Type | Text, bibliography |
| Format | print, xiii, 106 leaves : ill. ; 30 cm. |
| Rights | Use of this resource is governed by the terms and conditions of the Creative Commons “Attribution-NonCommercial-NoDerivatives 4.0 International” License (http://creativecommons.org/licenses/by-nc-nd/4.0/) |
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