The role of the labile methyl groups of betaine in the transmethylation reactions in the barley plants was investigated using carbon-14 methyl labelled betaine. The N-methyl groups of N-methyl tyramine, hordenine and choline were found to arise from betaine. Betaine was also administered to castor bean seedlings and the alkaloid ricinine Isolated. It was found that Its N- and 0- methyl groups did not arise from betaine methyl.
The origin of the methylenedioxy and N-methyl groups of the alkaloid protopine was also investigated by the tracer technique. Carbon-14 methyl labelled L- methionine, carbon-14 methyl labelled choline and carbon- 14 labelled sodium formate were fed to Dicentra species and the extent and position of labelling of the protopine molecule determined by degradation / Thesis / Master of Science (MS)
| Identifer | oai:union.ndltd.org:mcmaster.ca/oai:macsphere.mcmaster.ca:11375/28208 |
| Date | 10 1900 |
| Creators | Sribney, Michael |
| Contributors | Kirkwood, S, Chemistry |
| Source Sets | McMaster University |
| Language | English |
| Detected Language | English |
| Type | Thesis |
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