This thesis investigated a new group of poly(Bd)/poly(Bd-co-MAA) core-shell particles that were ionically crosslinked and cast as nanostructured ionomer films from aqueous dispersions. The new group of poly(Bd)/poly(Bd-co-MAA) core-shell particles were studied for structure-property relationships and morphology. The covalent crosslinking content in the core and the shell were varied at constant ionic crosslinking. Stress-strain data showed control of the nanostructured films. The chain transfer agent used during the preparation of the nanoparticles core-shells was shown to independently tune the mechanical properties of the films.
| Identifer | oai:union.ndltd.org:bl.uk/oai:ethos.bl.uk:626951 |
| Date | January 2014 |
| Creators | Tungchaiwattana, Somjit |
| Contributors | Saunders, Brian |
| Publisher | University of Manchester |
| Source Sets | Ethos UK |
| Detected Language | English |
| Type | Electronic Thesis or Dissertation |
| Source | https://www.research.manchester.ac.uk/portal/en/theses/a-study-of-particle-structure-and-film-formation-mechanism-on-the-mechanical-properties-of-synthetic-rubber-films(3014e013-bc99-4fbf-8282-5d13ed4251b3).html |
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