The thin-layer flow-cell incorporated an array of 32 gold strip electrodes in a serial configuration opposite a platinum counter electrode. The cell body was made of Macor glass ceramic. A photolithographic procedure for etching the Macor and a simple method of applying a gold ink was devised. Resistive feedback current-to-voltage converters independently controlled the potential difference between the electrodes of the array and the common counter electrode. A microcomputer and a customized high speed data acquisition interface recorded the current response of each electrode. An expression for the faradaic response of a single electrode within a rectangular flow channel was modified to predict the behavior of the multi-electrode flow-cell. The quinone/hydroquinone redox system was used to evaluate the performance of the detector. Summing the signals from the array when all electrodes were held at the same potential improved the signal-to-noise ratio. Hydrodynamic curves were reconstructed from the currents measured at each electrode when a ramp potential profile was applied to the array.
| Identifer | oai:union.ndltd.org:LACETR/oai:collectionscanada.gc.ca:QMM.75690 |
| Date | January 1988 |
| Creators | DeAbreu, Michael Paul |
| Publisher | McGill University |
| Source Sets | Library and Archives Canada ETDs Repository / Centre d'archives des thèses électroniques de Bibliothèque et Archives Canada |
| Language | English |
| Detected Language | English |
| Type | Electronic Thesis or Dissertation |
| Format | application/pdf |
| Coverage | Doctor of Philosophy (Department of Chemistry.) |
| Rights | All items in eScholarship@McGill are protected by copyright with all rights reserved unless otherwise indicated. |
| Relation | alephsysno: 000665147, proquestno: AAINL46040, Theses scanned by UMI/ProQuest. |
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