A paucity of literature exists on the Independent System analysis of adjacent, parallel transition dipoles. Applying this theory and certain spectral information semiemperical calculations were made to predict absorption profiles and band intensities. To aid in the assignment of the 7*+7 absorption bands it was necessary to obtain the vacuum ultraviolet spectra of cyclohexane and cyclohexene. Because the spectra of these molecules contained sharp, atomic-like absorption bands a Rydberg series could be fitted to certain absorptions, thus the determination of their ionization potentials. Using Independent System analysis profiles and intensities of 7*+q-- absorption bands ins 'several methyl substituted 1,4- cyclohexadienes and isotetralin were predicted where general agreement was found with observed experimental spectra.
| Identifer | oai:union.ndltd.org:unt.edu/info:ark/67531/metadc663526 |
| Date | 12 1900 |
| Creators | Tidwell, Edgar Rhea |
| Contributors | Russell, Benny, Jones, Paul R. |
| Publisher | North Texas State University |
| Source Sets | University of North Texas |
| Language | English |
| Detected Language | English |
| Type | Thesis or Dissertation |
| Format | iv, 62 leaves: ill., Text |
| Rights | Public, Tidwell, Edgar Rhea, Copyright, Copyright is held by the author, unless otherwise noted. All rights |
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