The Raman linewidths of the carbon-halogen stretching mode was measured as a function of temperature in ethyl bromide, isopropyl chloride, isopropyl bromide, t-butyl chloride, t-butyl bromide, chlorobenzene, bromobenzene, iodobenzene and o-dichlorobenzene. The vibrational relaxation times showed a very clear trend. Together with earlier work on methyl iodide, these results provide evidence that the vibrational dephasing efficiencies (T^-1_iso) of the carbon-halogen mode vary in the order of Cl > Br > I. Vibrational dephasing times were calculated from the Fischer-Laubereau Isolated Binary Collision Mode. If further work shows this transferability to extend to other types of skeletal modes in molecular systems, this would have significant ramifications on future vibrational lineshape studies.
| Identifer | oai:union.ndltd.org:unt.edu/info:ark/67531/metadc504376 |
| Date | 05 1900 |
| Creators | Ho, Salina Yuen-Han |
| Contributors | Schwartz, Martin, Theriot, L. J. |
| Publisher | North Texas State University |
| Source Sets | University of North Texas |
| Language | English |
| Detected Language | English |
| Type | Thesis or Dissertation |
| Format | v, 56 leaves : ill., Text |
| Rights | Public, Ho, Salina Yuen-Han, Copyright, Copyright is held by the author, unless otherwise noted. All rights reserved. |
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