Electrochemical and infrared spectral data for a number of octahedral systems of the type LM(CO)₅ (M=Cr, Mo) and W; L=pyridine and quinoline), L₂M(CO)₄ (M=Cr, Mo, and W; L₂ =ethylenediamine, (pyridine)₂, and bipyridyl), (LM(CO)₄)₂ (M=Cr, Mo, and W; L=As(CH₃)₂ and P(CH₃)₂) and (LFe(CO)₃)₂ (L=SCH₃ , P(CH₃)₂ , and As(CH₃)₂) before and after electrochemical reduction are presented. Force constants are calculated using the Cotton-Kraihanzel force field and the results discussed in terms of sigma and pi-bonding.
Infrared spectral data before and after electroche~ical reduction are also reported for a number of iron-olefin complexes of low symmetry. / M.S.
| Identifer | oai:union.ndltd.org:VTETD/oai:vtechworks.lib.vt.edu:10919/101408 |
| Date | January 1968 |
| Creators | Wieczorek, Leonard |
| Contributors | Chemistry |
| Publisher | Virginia Polytechnic Institute |
| Source Sets | Virginia Tech Theses and Dissertation |
| Language | English |
| Detected Language | English |
| Type | Thesis, Text |
| Format | vi, 84 leaves, application/pdf, application/pdf |
| Rights | In Copyright, http://rightsstatements.org/vocab/InC/1.0/ |
| Relation | OCLC# 07104655 |
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