The present dissertation consists of two thematically related parts. The first one (includes two publications) deals with the study of chemical pro- cesses and spectroscopy of highly reactive particles produced in the discharge plasma. This part includes the analysis of ro-vibronic CN radical transitions in the infrared region and the study of chemical reactions in pulsed dischar- ges. The discharge was used as a tool for research of decomposition of simple precursors (acetonitrile, formamide and BrCN) and the subsequent formation of intermediates and reaction products in plasma. The obtained experimental results were interpreted using a numerical model developed in context of this work and used to simulate the kinetics of the studied systems. The second part (includes seven works) is aimed at high-resolved spectro- scopy of metals in the ablation plasma. A total of six different metals were studied: Au, Ag, Cu, Cs, K and Na. The main motivation for spectroscopic research on metals in the infrared region is to obtain information on atomic metals transitions, which are particularly important for astronomical identi- fication of lines in the spectra of stars and their spectroscopic assignments. Each publication contains a summary of the analyzed atomic transitions of which a considerable portion had not...
| Identifer | oai:union.ndltd.org:nusl.cz/oai:invenio.nusl.cz:309491 |
| Date | January 2012 |
| Creators | Kubelík, Petr |
| Contributors | Civiš, Svatopluk, Wild, Jan, Rohlena, Karel |
| Source Sets | Czech ETDs |
| Language | Czech |
| Detected Language | English |
| Type | info:eu-repo/semantics/doctoralThesis |
| Rights | info:eu-repo/semantics/restrictedAccess |
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