The effects arising from quadratic electron-phonon interaction and anharmonicity on the optical spectra of imperfections in nonmetals are examined. The absorption or emission line-shape function is expressed in terms of Kubo's formula and is reduced to a trace over phonon states only via the application of the Barrie-Sharpe method. This trace is evaluated with the aid of quantum field-theoretic techniques. It is shown that both the quadratic electron-phonon interaction and anharmonicity modify the phonon spectrum, and the influence of this modification on the optical spectra is studied in detail with regard to position, intensity, width, Stokes' shift and mirror reflection symmetry. / Science, Faculty of / Physics and Astronomy, Department of / Graduate
| Identifer | oai:union.ndltd.org:UBC/oai:circle.library.ubc.ca:2429/20539 |
| Date | January 1977 |
| Creators | Chow, Hau-Cheung |
| Source Sets | University of British Columbia |
| Language | English |
| Detected Language | English |
| Type | Text, Thesis/Dissertation |
| Rights | For non-commercial purposes only, such as research, private study and education. Additional conditions apply, see Terms of Use https://open.library.ubc.ca/terms_of_use. |
Page generated in 0.0059 seconds