New corrole–BODIPY conjugates have been synthesized in high yield under mild conditions. Upon excitation at the absorption maximum of the BODIPY antenna chromophore, the fluorescence intensity of the free base corrole–BODIPY conjugate increases by ca. 300%, and significant phosphorescence intensity is observed for the iridium(III) complex of the conjugate, while almost no phosphorescence is observed for the parent iridium(III) corrole, due to through-bond energy transfer from the BODIPY antenna-chromophore to the corrole core. / Original publication is available at http://dx.doi.org/10.1039/c5ra07250f / Arbortext Advanced Print Publisher 9.1.510/W Unicode / Acrobat Distiller 8.1.0 (Windows); modified using iText� 5.3.3 �2000-2012 1T3XT BVBA (AGPL-version)
Identifer | oai:union.ndltd.org:netd.ac.za/oai:union.ndltd.org:rhodes/vital:7268 |
Date | 08 June 2015 |
Creators | Chen, Wei, Zhang, Jianfeng, Mack, John, Kubheka, Gugu, Nyokong, Tebello, Shen, Zhen, Wei Chen |
Publisher | Royal Society of Chemistry |
Source Sets | South African National ETD Portal |
Language | English |
Detected Language | English |
Type | Article |
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