Crystals of the title compound are monoclinic with a= 8.314 (5), b= 22.723 (9), c= 12.589 (6) A, /3= 123.0 (2t, Z=4, space group P2dc. The structure was determined by Patterson and Fourier methods and refined by full-matrix least squares to a final R of 0.030 for 2043 independent reflexions. The U atom has pentagonal bipyramidal coordination and the N-methylacetylacetoneamine is bonded to U via O. There are two intramolecular N-H. . .0 hydrogen bonds which govern the geometry of the adduct molecule.
| Identifer | oai:union.ndltd.org:netd.ac.za/oai:union.ndltd.org:rhodes/vital:6373 |
| Date | January 1976 |
| Creators | Haigh, J M, Nassimbeni, L R, Pauptit, R A, Rodgers, A L, Sheldrick, G M |
| Source Sets | South African National ETD Portal |
| Language | English |
| Detected Language | English |
| Type | Article, text |
| Format | 4 pages, pdf |
Page generated in 0.0018 seconds