Part I: Pyrrolidine derivatives were attached a methoxy group on a-C position of pyrrolidine-ring via anodic oxidation. Followed with alkylation and series of transformation under Lewis acids to obtain tropane alkaloids.
Part II: Application of intramolecular radical cyclization toward the synthesis of aporphine alkaloids. Tributyltinhydride and AIBN were used to generate aryl radicals. Trapping of aryl radicals with unsaturated alkenes led to products.
| Identifer | oai:union.ndltd.org:NSYSU/oai:NSYSU:etd-0707100-112135 |
| Date | 07 July 2000 |
| Creators | Chou, Wu-Sen |
| Contributors | Chi-Wi Ong, Chih-Shone Lee, Chin-Hsing Chou |
| Publisher | NSYSU |
| Source Sets | NSYSU Electronic Thesis and Dissertation Archive |
| Language | Cholon |
| Detected Language | English |
| Type | text |
| Format | application/pdf |
| Source | http://etd.lib.nsysu.edu.tw/ETD-db/ETD-search/view_etd?URN=etd-0707100-112135 |
| Rights | not_available, Copyright information available at source archive |
Page generated in 0.0017 seconds