Porovnání základních analytických charakteristik stanovení jednotlivých specií selenu při chemickém a elektrochemickém generování jejich těkavých forem s detekcí AFS / Comparison of basic analytical characteristics of determination for each species of selenium in the chemical and electrochemical hydride generation of selenium species with AFS detection

Description

This thesis deals with the further development of the technique of generation of volatile compounds as derivatization methods by speciation analysis of selenium compounds. Specifically, this diploma thesis compares technique chemical and electrochemical generation of selected species of selenium (inorganic Se (IV) inorganic Se (VI), selenomethionine (Se- Met), selenocysteine (Se-Cys), methyl-selenocysteine (Met-Se-Cys) and seleno-urea (Se-U)). The achieved basic analytical characteristics are compared of each species in non-column arrangement with atomic fluorescence spectrometry. The effect of pre- reduction/decomposition unit are tested, using the pre-reduction agent KBr and hydrochloric acid at higher temperature and in the presence of UV radiation. Keywords Selenium, speciation analysis, chemical hydride generation, electrochemical hydride generation, atomic fluorescence spectrometry

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1. http://www.nusl.cz/ntk/nusl-344008

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Additional Fields

Identifer	oai:union.ndltd.org:nusl.cz/oai:invenio.nusl.cz:344008
Date	January 2016
Creators	Šáriczká, Michaela
Contributors	Rychlovský, Petr, Hraníček, Jakub
Source Sets	Czech ETDs
Language	Slovak
Detected Language	English
Type	info:eu-repo/semantics/masterThesis
Rights	info:eu-repo/semantics/restrictedAccess