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Mechanochemical dehydrocoupling of dimethylamine borane and hydrogenation reactions using Wilkinson's catalyst

No / Mechanochemistry enabled the selective synthesis of the recherche´
orange polymorph of Wilkinson’s catalyst [RhCl(PPh3)3]. The mechanochemically prepared Rh-complex catalysed the solvent-free dehydrogenation of Me2NHBH3 in a ball mill. The in situ-generated hydrogen
(H2) could be utilised for Rh-catalysed hydrogenation reactions by ball
milling. / We thank the RWTH Aachen University for support from the Distinguished Professorship Program funded by the Excellence Initiative of the German federal and state governments, and the EPSRC for funding (EP/L019655/1).

Identiferoai:union.ndltd.org:BRADFORD/oai:bradscholars.brad.ac.uk:10454/17697
Date03 March 2020
CreatorsSchumacher, C., Crawford, Deborah E., Raguž, B., Glaum, R., James, S.L., Bolm, C., Hernández, J.G.
Source SetsBradford Scholars
LanguageEnglish
Detected LanguageEnglish
TypeArticle, No full-text in the repository

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