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Synthesis and structural studies of metallacycles.

Kathleen Shuk Man Poon. / Thesis (M.Phil.)--Chinese University of Hong Kong, 1994. / Includes bibliographical references (leaves 93-94). / Abbreviations --- p.v / Lists of Figures --- p.vi / Lists of Schemes --- p.vii / Lists of Tables --- p.viii / Part I / Chapter Chapter 1 --- Introduction --- p.2 / Chapter 1.1 --- Thermal stability of metallacycles --- p.2 / Chapter 1.2 --- General Synthetic methods of Metallacycle --- p.5 / Chapter 1.3 --- Objective of this work --- p.6 / Chapter 1.4 --- Features of Ligands --- p.6 / Chapter 1.5 --- References --- p.10 / Chapter Chapter 2 --- Synthesis of Transfer Reagents --- p.11 / Chapter 2.1 --- Brief Survey of various Transfer Reagents --- p.11 / Chapter 2.2 --- Introduction to metallation reaction --- p.13 / Chapter 2.3 --- Result and Discussion --- p.16 / Chapter 2.3.1 --- Lithiation and Derivatization of Ligand --- p.16 / Chapter 2.3.2 --- Charge Migration --- p.18 / Chapter 2.3.3 --- Characterization of compounds --- p.23 / Chapter 2.4 --- Experimental --- p.27 / Chapter 2.5 --- References --- p.33 / Chapter Chapter 3 --- Synthesis of Metallacycles --- p.35 / Section I --- p.35 / Chapter 3.1 --- Introduction --- p.35 / Chapter 3.2 --- Results and Discussion --- p.36 / Chapter 3.2.1 --- Synthesis of Metallacycles of Group 14 elements --- p.36 / Chapter 3.2.2 --- Characterization of Group 14 metallacycles --- p.42 / Chapter 3.2.3 --- Experimental --- p.57 / Section II --- p.64 / Chapter 3.3 --- Introduction --- p.64 / Chapter 3.4 --- Result and Discussion --- p.65 / Chapter 3.4.1 --- Synthesis of Metallacycles of Group 4 elements --- p.65 / Chapter 3.4.2 --- Experimental --- p.68 / Chapter 3.5 --- Attempted synthesis of Group 12 Metallacycles --- p.70 / Chapter 3.5.1 --- Results and Discussion --- p.70 / Chapter 3.5.2 --- Experimental --- p.71 / Chapter 3.6 --- References --- p.73 / Part II --- p.75 / Chapter Chapter 4 --- Synthesis of Bimetallic Complex --- p.76 / Chapter 4.1 --- Brief Review on Bimetallic Complexes --- p.76 / Chapter 4.2 --- Results and Discussion --- p.80 / Chapter 4.2.1 --- Synthesis of bimetallic complexes --- p.80 / Chapter 4.2.2 --- Characterization of bimetallic complexes --- p.87 / Chapter 4.2.3 --- Experimental --- p.90 / Chapter 4.3 --- References --- p.93 / Appendix I General Experimental Procedure --- p.95

Identiferoai:union.ndltd.org:cuhk.edu.hk/oai:cuhk-dr:cuhk_318127
Date January 1994
ContributorsPoon, Kathleen Shuk Man., Chinese University of Hong Kong Graduate School. Division of Chemistry.
PublisherChinese University of Hong Kong
Source SetsThe Chinese University of Hong Kong
LanguageEnglish
Detected LanguageEnglish
TypeText, bibliography
Formatprint, viii, 96 leaves : ill. ; 30 cm.
RightsUse of this resource is governed by the terms and conditions of the Creative Commons “Attribution-NonCommercial-NoDerivatives 4.0 International” License (http://creativecommons.org/licenses/by-nc-nd/4.0/)

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