It was proposed to study the cycloaddition of ketenes and carbodiimides in some detail. The first objective was to investigate the general applicability of the reaction as a tool for the synthetic organic chemist in the preparation of a new class of substituted β-lactams; i.e., imino-β-lactams. It was proposed for this part of the research problem to look for the intermediate, either directly or indirectly, by trapping experiments. It was further proposed to study substituent effects in the ketene and carbodiimide and also Investigate the effect of solvent polarity on the reaction rate. From these data, it was hoped that the mechanism of the cycloaddition reaction could be elucidated.
| Identifer | oai:union.ndltd.org:unt.edu/info:ark/67531/metadc164432 |
| Date | 08 1900 |
| Creators | Dorsey, Edwin Darrell |
| Contributors | Brady, William Thomas, Skinner, Charles Gordon, Truitt, Price, Glaze, William |
| Publisher | North Texas State University |
| Source Sets | University of North Texas |
| Language | English |
| Detected Language | English |
| Type | Thesis or Dissertation |
| Format | v, 51 leaves: ill., Text |
| Rights | Public, Copyright, Copyright is held by the author, unless otherwise noted. All rights reserved., Dorsey, Edwin Darrell |
Page generated in 0.0021 seconds