In this master thesis 1,2-disubstituted cyclopentadienes were prepared by method composed of three transition metal catalysed reactions. Then, the cyclopentadienes were converted into cyclopentadienyl manganese, rhenium and iron complexes. A one-pot synthesis of the cyclopentadienyl metal complexes was developed without isolation of the intermediate cyclopentadienes. The second goal of this thesis was preparation of vinyl-substituted cyclopentadienes using ring closing enyne metathesis. The last part of thesis dealt with synthesis of a chiral cyclopentadiene and preparation of the corresponding metal complexes. The important part of this work was preparation of starting materials using palladium catalysed cross-coupling reactions. Key words: cyclopentadienes, carbometallation, cross-coupling, metathesis, metallocenes.
Identifer | oai:union.ndltd.org:nusl.cz/oai:invenio.nusl.cz:388185 |
Date | January 2018 |
Creators | Vician, Marek |
Contributors | Kotora, Martin, Míšek, Jiří |
Source Sets | Czech ETDs |
Language | Slovak |
Detected Language | English |
Type | info:eu-repo/semantics/masterThesis |
Rights | info:eu-repo/semantics/restrictedAccess |
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